[Zn2(O2CMe)2(μ-O2CMe)(μ-2-hydroxyethyl-bis(2-(pyrid-2-yl)ethyl)amine-H)] | 959772-37-3

• 英文名称: [Zn2(O2CMe)2(μ-O2CMe)(μ-2-hydroxyethyl-bis(2-(pyrid-2-yl)ethyl)amine-H)]
• CAS: 959772-37-3
• 化学式: C₂₂H₂₉N₃O₇Zn₂
• 分子量: 578.268
• InChiKey: MQGPGPJCBSAVAL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N-bis[2-(2-pyridyl)ethyl]ethanolamine 、 zinc(II) acetate dihydrate 以 氯仿 为溶剂， 以51%的产率得到[Zn2(O2CMe)2(μ-O2CMe)(μ-2-hydroxyethyl-bis(2-(pyrid-2-yl)ethyl)amine-H)]
  参考文献：
  名称：

  Mononuclear and unsymmetric dinuclear complexes of the tripodal ligand 2-hydroxyethyl-bis(2-{pyrid-2-yl}ethyl)amine

  摘要：

  Reaction of bis(2-{pyrid-2-yi} ethyl) amine with 2-bromoethanol in the presence of Na2CO3 yields the title ligand, LH. Treatment of LH with the CuBr2 or Zn(O2CMe)(2) center dot 2H(2)O yields pure crystalline [CuBr(LH)]Br center dot H2O (1 center dot H2O) and [Zn-2(O2CMe)(2)(mu-O2CMe)(mu-L)] (2). Reaction of LH with Cu(O2CMe)(2) H2O affords a low yield Of [Cu2Cl2(mu-O2CMe)(mu-L)] (3), the Cl- ligands apparently originating from the CH2Cl2 crystallization solvent. Compound 1 center dot H2O is a near-regular square-pyramidal complex with a neutral, protonated LH ligand. In contrast, 2 and 3 are both unusual unsymmetric dinuclear complexes, with a five-coordinate [ML(O2CMe)] (M = Zn or Cu) unit linked to a second metal ion through the deprotonated ligand alkoxide donor and O,O'-bridging acetate ligand. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.04.046