| 377092-59-6

• CAS: 377092-59-6
• 化学式: C₇₄H₉₂Cl₄F₁₈Li₂Mo₂N₄O₄
• 分子量: 1791.11
• InChiKey: BJULFVGCCMLBTF-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯双[（2,6-二异丙基苯基）亚氨基]（1,2-二甲氧基乙烷）钼（VI） 、 2,4,6-tris(trilfuoromethyl)phenyllithium 以 乙醚 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structures of chromium and molybdenum complexes containing the 2,4,6-tris(trifluoromethyl)phenyl ligand

  摘要：

  Complexes [Cr(NR)(2)Cl-2] react with Li(fmes) to yield [Cr(NR)(2)(fmes)(2)], where fmes = 2,4,6-(CF3)(3)C6H2. X-ray diffraction studies of the newly synthesised complex with R = adamantyl, and the previously known one with R = tert-butyl, have revealed tetrahedral coordination of the metal, complemented by two secondary (CrF)-F-... interactions with ortho-CF, groups of the fmes ligands. The reaction of [Mo(NC6H3' Pr-2-2,6)(2)Cl-2(dme)] with Li(fines) gave a dimeric complex [Mo(NC6H3' Pr-2-2,6)(2)(fmes)Cl-LiCl(dme)](2). The X-ray structure of the latter (as its pentane solvate) shows a double-ribbon Mo2Li2Cl4 arrangement, with two Cl atoms mu (2)-bridging between Mo and Li, and two others mu (3)-bridging between one Mo and two Li atoms. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01063-4