| 937801-64-4

• CAS: 937801-64-4
• 化学式: C₂₇H₂₇Cl₂NP₂Pd
• 分子量: 604.792
• InChiKey: FGSYGUFXAIJEFO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 bis((diphenylphosphino)methyl)methylamine 以 二氯甲烷 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Synthesis of palladium complexes with bis(diphenylphosphinomethyl)amino ligands: A catalyst for the Heck reaction of aryl halide with methyl acrylate

  摘要：

  A series of ligands, (Ph2PCH2)(2)NR (R = -CH3) (1), -C(CH3)(3), (2) -m-C6H4SO3Na (3), and their Pd(II) complexes have been synthesized under nitrogen atmosphere using Schlenk method. All compounds were characterized using elemental analysis and spectroscopic techniques (AAS, NMR (H-1, P-31)). Based on the analysis the complexes have been proposed as in square planar geometry. The Pd(II) complexes were applied to the Heck reaction of aryl halide (Br, Cl) with methyl acrylate. The results have exhibited that complexes [PdCl2((Ph2PCH2)(2)NCH3)] (4) and [PdCl2((Ph2PCH2)(2)NC(CH3)(3))] (5) have shown higher turnover numbers (TON) than complex [PdCl2(Ph2PCH2)(2)N-m-C6H4SO3Na] (6). (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.01.003