η(2)-(N,C)-2-(N(2)-cyclohexylidene-N(1)-phenylhydrazino)phenyltetracarbonylmanganese | 213816-49-0

• 英文名称: η(2)-(N,C)-2-(N(2)-cyclohexylidene-N(1)-phenylhydrazino)phenyltetracarbonylmanganese
• CAS: 213816-49-0
• 化学式: C₂₂H₁₉MnN₂O₄
• 分子量: 430.342
• InChiKey: XCLSTYBYHKIEAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  benzylpentacarbonylmanganese 、 cyclohexanone diphenylhydrazone 以 正庚烷 为溶剂， 以94%的产率得到η(2)-(N,C)-2-(N(2)-cyclohexylidene-N(1)-phenylhydrazino)phenyltetracarbonylmanganese
  参考文献：
  名称：

  Orthomanganation of arylhydrazones and related N-donor substrates

  摘要：

  The N-phenyl- and N,N-diphenylhydrazones of benzaldehyde or acetophenone are readily cyclometallated on reaction with PhCH2Mn(CO)(5) to give complexes 3 of the type (OC)(4)MnC6H4C(R-1)=NNPhR2 incorporating a five-membered MnC3N ring. The example with R-1 = Me, R-2 = H has been structurally characterised. The similar reaction with the N,N-diphenylhydrazone of cyclohexanone produces a species with an alternative MnC2N2 ring which was also structurally characterised. A related species (OC)(4)MnC6H4NN=O is formed from N-nitrosodiphenylamine. Reactions of compounds 3 from the diphenylhydrazones with alkynes PhC=CPh or Me3SiC=CH give N'-indenyl-N,N-diphenylhydrazines in reasonable yields. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00453-7