1,4-bis(hydroxymethyl)perfluorocyclohexane | 105136-42-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,4-bis(hydroxymethyl)perfluorocyclohexane
• 英文别名: [1,2,2,3,3,4,5,5,6,6-Decafluoro-4-(hydroxymethyl)cyclohexyl]methanol
• CAS: 105136-42-3
• 化学式: C₈H₆F₁₀O₂
• 分子量: 324.118
• InChiKey: UXZWSFZGBOFZKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,4-bis(hydroxymethyl)perfluorocyclohexane 、 甲基丙烯酰氯 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 2.0h， 以89%的产率得到1,4-bis(methacryloyloxymethyl)perfluorocyclohexane
  参考文献：
  名称：

  JP2005/350355

  摘要：

  公开号：
• 作为产物：
  描述：

  1,4-dimethoxycarbonylperfluorocyclohexane 在 sodium tetrahydroborate 、 盐酸 、 水 作用下， 以 乙醇 为溶剂， 以12%的产率得到1,4-bis(hydroxymethyl)perfluorocyclohexane
  参考文献：
  名称：

  JP2005/350355

  摘要：

  公开号：

文献信息

• Perfluorocycloalkane carbonyl fluorides and their derivatives
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0190847A2

  公开（公告）日：1986-08-13

  Di- and tri-substituted perfluorocycloalkane compounds which have a cyclohexane or decahydronaphthalene nucleus are provided. These perfluorocycloalkane compounds are carbonyl fluorides and derivatives thereof.

  提供了具有环己烷或十氢萘核的二取代和三取代全氟环烷烃化合物。这些全氟环烷烃化合物是羰基氟化物及其衍生物。
• NOVEL CROSSLINKABLE FLUORINE-CONTAINING ETHER COMPOUND
  申请人：ITO Takayuki

  公开号：US20080255337A1

  公开（公告）日：2008-10-16

  A crosslinkable fluorine-containing compound, which is an adduct compound having a crosslinkable group, wherein the adduct compound is an adduct of a fluorine-containing compound having, per molecule, 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom.
• NOVEL FLUORINE-CONTAINING POLYMER AND METHOD OF PRODUCING FLUORINE-CONTAINING POLYMER
  申请人：Ito Takayuki

  公开号：US20090318650A1

  公开（公告）日：2009-12-24

  A method of producing a fluorine-containing polymer, containing conducting an addition polymerization of a fluorine-containing compound having 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom per molecule, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom; and a fluorine-containing polymer comprising a repeating unit represented by formula (i): wherein Rf 1 represents a perfluoroalkylene group; each of Rf 2 and Rf 3 independently represents a fluorine atom, a perfluoroalkyl group or a perfluoroalkoxy group; at least two among Rf 1 , Rf 2 and Rf 3 may bond to each other to form a ring structure; X represents an oxygen atom or a sulfur atom; and L represents a divalent organic group.
• US4739103A
  申请人：——

  公开号：US4739103A

  公开（公告）日：1988-04-19
• US8119765B2
  申请人：——

  公开号：US8119765B2

  公开（公告）日：2012-02-21