[(η(6)-p-cymene)RuCl(PPh(2,6-(MeO)2C6H3)(2-O-6-MeOC6H3))2]*CH2Cl2 | 176301-00-1

• 英文名称: [(η(6)-p-cymene)RuCl(PPh(2,6-(MeO)2C6H3)(2-O-6-MeOC6H3))2]*CH2Cl2
• CAS: 176301-00-1
• 化学式: CH₂Cl₂*C₃₁H₃₄ClO₄PRu
• 分子量: 723.038
• InChiKey: PKMUARXQOKBMGN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 Bis-(2,6-dimethoxyphenyl)-phenyl-phosphin 以 not given 为溶剂， 以66%的产率得到[(η(6)-p-cymene)RuCl(PPh(2,6-(MeO)2C6H3)(2-O-6-MeOC6H3))2]*CH2Cl2
  参考文献：
  名称：

  Arene ruthenium(II) complexes coordinated by phosphino and two phenoxide groups in tris(2,6-dimethoxyphenyl)phosphine: crystal structure of (η6-1,2,3,4-Me4C6H2)Ru[P[lcub]2,6-(MeO)2C6H3[rcub] [lcub]2-O-6-MeOC6H3[rcub;]2]

  摘要：

  The title compound has been prepared from bis[dichloro(eta(6)-arene)ruthenium] (eta(6)-arene = 1,2,3,4-C(6)Me(4)H(2) (1a), p-cymene (1b) and tris(2,6-dimethoxyphenyl)phospine (TDMPP). The crystal structure features a type of eta(3)-phosphino-two phenoxides coordination. Reactions with its related phosphines, bis(2,6-dimethoxyphenyl)phenylphosphine (BDMPP) and (2,6-dimethoxyphenyl)diphenylphosphine (MDMPP) gave complexes with eta(2)-phosphino-phenoxide and eta(1)-phosphino coordinations, and trans-RuCl2(MDMPP)(2), depending on phosphines and arene groups.

  DOI：

  10.1016/0022-328x(94)05334-8