{Rh(CN-t-Bu)4}PF6 | 42744-96-7

• 英文名称: {Rh(CN-t-Bu)4}PF6
• CAS: 42744-96-7
• 化学式: C₂₀H₃₆N₄Rh*F₆P
• 分子量: 580.402
• InChiKey: JIXOLRABTNQPSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Rh(CN-t-Bu)4}PF6 、 1,5-二(二叔丁基膦)戊烷 以 丙酮 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Crocker, Christopher; Errington, R. John; Markham, Richard, Journal of the Chemical Society, Dalton Transactions, 1982, p. 387 - 396

  摘要：

  DOI：

文献信息

• Balch, Alan L.; Catalano, Vincent J., Inorganic Chemistry, 1992, vol. 31, # 19, p. 3934 - 3942
  作者：Balch, Alan L.、Catalano, Vincent J.

  DOI：——

  日期：——
• Assignment of the luminescing states of [AuIRhI(tBuNC)2(.mu.-dppm)2][PF6]2
  作者：D. R. Striplin、G. A. Crosby

  DOI：10.1021/j100028a001

  日期：1995.7

  Fluorescence, phosphorescence, and excitation spectra were measured on the title compound. These results were augmented with polarization ratios obtained at 77 K and detailed studies of the temperature dependence of the phosphorescence in the 77-4 K range. The phosphorescence decay rate at 4 K was also recorded as a function of an applied magnetic field. Ah the results are consistent with a 4d(2)Rh(1) --> 6p(z)Au(1) orbital promotion leading to emitting (1)A(1), (3)A(1) terms in pseudo-C-2v symmetry. The (3)A(1) term is split by spin-orbit coupling into a forbidden A(2) state lying lowest followed by a quasi-degenerate pair, [B-i(x), B-2(y)] lying similar to 16 cm(-1) higher that decays >500 times faster than the lowest one.