[Ru(BINAP)H(tri(p-tolyl)phosphine)]OTf | 643742-25-0

• 英文名称: [Ru(BINAP)H(tri(p-tolyl)phosphine)]OTf
• CAS: 643742-25-0
• 化学式: CF₃O₃S*C₆₅H₅₄P₃Ru
• 分子量: 1178.21
• InChiKey: VAFDCHZTURSXRG-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [Ru(BINAP)H(η6-benzene)]OTf 、 三对苯甲基膦 以 1,2-二氯乙烷 为溶剂， 生成 [Ru(BINAP)H(tri(p-tolyl)phosphine)]OTf
  参考文献：
  名称：

  Binap as an 8e arene-mono-phosphine donor to Ru(II)

  摘要：

  The reaction of the cationic hydride complex [RuH(eta(6)-benzene)(Binap)]CF3SO3 with PPh3 at 80 degreesC afforded complex 4 in excellent yield. The reaction with tri(p-tolyl) phosphine afforded an analogous compound, 5. After loss of the complexed benzene, the Ru-cation generated chooses to stabilize itself by coordinating the proximate naphthyl ring at the expense of one of the two phosphorus donors. The solid-state structure of 4 is reported and reveals that the eta(6) arene is strongly distorted towards a eta(4)-mode. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00393-1