T(p-OH)PPMnCl | 186697-67-6

• 英文名称: T(p-OH)PPMnCl
• 英文别名: 5,10,15,20-tetrakis(p-hydroxyphenyl)-21H,23H-porphyrin manganese(III) chloride；manganese(III) tetra(p-hydroxyphenyl)porphyrin chloride
• CAS: 186697-67-6
• 化学式: C₄₄H₂₈ClMnN₄O₄
• 分子量: 767.122
• InChiKey: DFYCNGVKJULKJX-YKKPBKTHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.5h， 以81.9%的产率得到T(p-OH)PPMnCl
  参考文献：
  名称：

  A Green Process for Oxidation of p-Nitrotoluene Catalyzed by Metalloporphyrins under Mild Conditions

  摘要：

  A novel synthetic technology of p-nitrobenzoic acid has been investigated with dioxygen by using metalloporphyrins RTPP-(MCl)-Cl-III (M = Fe, Co, Mn) as biomimetic catalysts. Oxidation of p-nitrotoluene to p-nitrobenzoic acid under 2.0 MPa of O-2 in the presence of a microamount of metalloporphyrins (RTPP-(MCl)-Cl-III) at 55 degrees C was achieved with the highest ( up to 90.4%) yield. Further research results show that the catalytic activities were relative to the nature of the substituted groups and the central metal ions of metalloporphyrins. For the metalloporphyrins with the same center metal ions, the greater the electron-withdrawing degree of groups in the porphyrin ring, the higher the catalytic activities of the metalloporphyrins. The catalytic activities for metalloporphyrins with different center metal ions followed the order RTPPMn Cl-III > RTPP (FeCl)-Cl-III > RTPP (CoCl)-Cl-III.

  DOI：

  10.1021/op060056z