(η5-2,5-Me2-3,4-Ph2C5OH)RuI(CO)2 | 1174232-39-3

• 英文名称: (η5-2,5-Me2-3,4-Ph2C5OH)RuI(CO)2
• CAS: 1174232-39-3
• 化学式: C₂₁H₁₇IO₃Ru
• 分子量: 545.339
• InChiKey: JGLYVODMBBDCMM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 、 (η5-2,5-Me2-3,4-Ph2C5OH)RuI(CO)2 以 二氯甲烷 为溶剂， 以91%的产率得到[(Ru(CO)2(η5-2,5-Me2-3,4-Ph2C5OH))(Ru(CO)2(η4-2,5-Me2-3,4-Ph2C5O))(μ-I)]*2dichloromethane
  参考文献：
  名称：

  Formation of an Iodide-Bridged Diruthenium Complex from [(η⁵-Ph₄C₄COH)(CO)₂RuI] and [(Ph₄C₄CO)(CO)₂Ru]₂: An Efficient Catalyst for Alcohol Oxidation with Ag₂O

  摘要：

  Iodide-bridged diruthenium complexes [(n(5) -2.5-R-2-3.4-Ph2C4COH) (CO)(2) Ru-(mu-I)-Ru(CO)(2)(n(4)-2.5-R-2-3.4-Ph2C4CO)] (6a, R=ph; 6b, R=Me) were formed from the reaction of (n(5-)2.5-3.4-Ph2C4COH)(CO)(2) RuI (2c, R=Ph;2d, R=Me) with [(2.5-R(2-)3.4-Ph2C4CO)(CO)(2)Ru](2) (7a, R=Ph; 7b, R=Me). The complexes exhibited a high catalytic activity for the oxidation of alcohols with silver oxide at room temperature.

  DOI：

  10.1021/om9003434
• 作为产物：
  描述：

  碘仿 、 [(η4-2,5-Me2-3,4-Ph2C5OH)Ru(CO)3] 以 异丙醇 、 甲苯 为溶剂， 生成 (η5-2,5-Me2-3,4-Ph2C5OH)RuI(CO)2
  参考文献：
  名称：

  Formation of an Iodide-Bridged Diruthenium Complex from [(η⁵-Ph₄C₄COH)(CO)₂RuI] and [(Ph₄C₄CO)(CO)₂Ru]₂: An Efficient Catalyst for Alcohol Oxidation with Ag₂O

  摘要：

  Iodide-bridged diruthenium complexes [(n(5) -2.5-R-2-3.4-Ph2C4COH) (CO)(2) Ru-(mu-I)-Ru(CO)(2)(n(4)-2.5-R-2-3.4-Ph2C4CO)] (6a, R=ph; 6b, R=Me) were formed from the reaction of (n(5-)2.5-3.4-Ph2C4COH)(CO)(2) RuI (2c, R=Ph;2d, R=Me) with [(2.5-R(2-)3.4-Ph2C4CO)(CO)(2)Ru](2) (7a, R=Ph; 7b, R=Me). The complexes exhibited a high catalytic activity for the oxidation of alcohols with silver oxide at room temperature.

  DOI：

  10.1021/om9003434