[(dtbpe)Ni(σ-HBEt2)] | 874340-34-8

• 英文名称: [(dtbpe)Ni(σ-HBEt2)]
• CAS: 874340-34-8
• 化学式: C₂₂H₅₁BNiP₂
• 分子量: 447.095
• InChiKey: XRUVYLUEWBAQMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硼烷四氢呋喃络合物 、 [Ni(1,2-bis(di-tert-butylphosphino)ethane)(μ-H)]2 、 三乙基硼 以 四氢呋喃 为溶剂， 以10%的产率得到[(dtbpe)Ni(σ-HBEt2)]
  参考文献：
  名称：

  σ-Borane Coordinated to Nickel(0) and Some Related Nickel(II) Trihydride Complexes

  摘要：

  The reactions of the complexes [(dcype)NiH](2), 1, [(dippe)NiH](2), 2, and [(dtbpe)NiH](2), 3, with a mixture of BEt3 and Super-Hydride (LiHBEt3) afforded sigma-borane nickel(O) compounds of the type [(dcype)Ni(sigma-HBEt2)], 4, [(dippe)Ni(sigma-HBEt2)], 5, [(dtbpe)Ni(sigma-HBEt2)], 6, respectively, with the concomitant formation in each case of [(dcype)(2)Ni-2(H)(3)][BEt4], 7, [(dippe)(2)Ni-2(H)(3)][BEt4], 8 and [(dtbpe)(2)Ni-2(H)(3)][BEt4], 9, respectively. X-ray crystal structures are reported for 4 and 8. The reaction of BEt3 and LiHBEt3 was also reviewed in detail.

  DOI：

  10.1021/ja056000m