Fe2(μ-Sn(tert-butyl)2)2(CO)8 | 40827-47-2

• 英文名称: Fe2(μ-Sn(tert-butyl)2)2(CO)8
• 英文别名: Fe2(μ-Sn(Bu(t))2)2(CO)8
• CAS: 40827-47-2
• 化学式: C₂₄H₃₆Fe₂O₈Sn₂
• 分子量: 801.659
• InChiKey: RUIURTOPAPRIJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氘代甲苯 、 Fe2(μ-Sn(tert-butyl)2)2(CO)8 以 氘代甲苯 为溶剂， 以1%的产率得到Fe2(μ-Sn(tert-butyl)(benzyl deuterated))2(CO)8
  参考文献：
  名称：

  Selective benzylic C–H activation of solvent toluene and m-xylene by an iron–tin cluster complex: Fe2(μ-)2(CO)8

  摘要：

  The bimetallic cluster complex Fe-2(mu-SnBu2t)(2)(CO)(8), 1, selectively activates the benzylic C-H bond in solvent toluene at reflux conditions to afford the complex Fe-2[mu-SnBut(CH2Ph)](2)(CO)(8), 3, where two of the But groups in 1 have been replaced with benzyl groups. Similarly 1 also activates the benzylic C-H bond in solvent m-xylene to yield complexes Fe-2[mu-SnBut(m-CH2PhMe)](2)(CO)(8), 4, Fe-2[mu-SnBut(m-CH2PhMe)][mu-Sn(m-CH2PhMe)(2)](CO)(8), 5, and Fe-2[mu-Sn(m-CH2PhMe)(2)](2)(CO)(8), 6, where two, three and four of the Bu-t groups in 1 have been replaced by m-tolyl groups, respectively. A mechanism based on a radical pathway is proposed for the C-H activation by 1. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.09.024
• 作为产物：
  描述：

  diiron nonacarbonyl 、 tri-tert-butylstannane 以 甲苯 为溶剂， 以41%的产率得到Fe2(μ-Sn(tert-butyl)2)2(CO)8
  参考文献：
  名称：

  Selective benzylic C–H activation of solvent toluene and m-xylene by an iron–tin cluster complex: Fe2(μ-)2(CO)8

  摘要：

  The bimetallic cluster complex Fe-2(mu-SnBu2t)(2)(CO)(8), 1, selectively activates the benzylic C-H bond in solvent toluene at reflux conditions to afford the complex Fe-2[mu-SnBut(CH2Ph)](2)(CO)(8), 3, where two of the But groups in 1 have been replaced with benzyl groups. Similarly 1 also activates the benzylic C-H bond in solvent m-xylene to yield complexes Fe-2[mu-SnBut(m-CH2PhMe)](2)(CO)(8), 4, Fe-2[mu-SnBut(m-CH2PhMe)][mu-Sn(m-CH2PhMe)(2)](CO)(8), 5, and Fe-2[mu-Sn(m-CH2PhMe)(2)](2)(CO)(8), 6, where two, three and four of the Bu-t groups in 1 have been replaced by m-tolyl groups, respectively. A mechanism based on a radical pathway is proposed for the C-H activation by 1. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.09.024