[μ-1κ2-O,O':2(η5)-cyclopentadienylcarboxylato][2(η5)-diphenylphosphinocyclopentadienyl]bis[1,1(η5)-tetramethylcyclopentadienyl]iron(II)titanium(III) | 429686-99-7

• 英文名称: [μ-1κ2-O,O':2(η5)-cyclopentadienylcarboxylato][2(η5)-diphenylphosphinocyclopentadienyl]bis[1,1(η5)-tetramethylcyclopentadienyl]iron(II)titanium(III)
• CAS: 429686-99-7
• 化学式: C₄₁H₄₄FeO₂PTi
• 分子量: 703.5
• InChiKey: FSMCVOZQSRXMGL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1′-(diphenylphosphino)ferrocene-1-carboxylic acid 、 [(η(5)-C5Me4H)2Ti(η(2)-bis(trimethylsilyl)ethyne)] 以 甲苯 为溶剂， 以84%的产率得到[μ-1κ2-O,O':2(η5)-cyclopentadienylcarboxylato][2(η5)-diphenylphosphinocyclopentadienyl]bis[1,1(η5)-tetramethylcyclopentadienyl]iron(II)titanium(III)
  参考文献：
  名称：

  [μ-1κ²O,O′:2(η⁵)-Cyclopentadienylcarboxylato][2(η⁵)-diphenylphosphinocyclopentadienyl]bis[1,1(η⁵)-tetramethylcyclopentadienyl]iron(II)titanium(III)

  摘要：

  Reacting stoichiometric amounts of 1-(diphenylphosphino)ferrocenecarboxylic acid and [Ti(eta(5)-C5HMe4)(2)(eta(2)-Me3SiC=CSiMe3)] produced the title carboxylatotitanocene complex, [{mu-1kappa(2)O,O':2(eta(5))-C5H4CO2}{2(eta(5))-C5H4P(C6H5)(2)}{1(eta(5))-C5H(CH3)(4)}(2)(FeTiIII)-Ti-II] or [FeTi(C9H13)(2)(C6H4O2)(C17H14P)]. The angle subtended by the Ti/O/O' plane, where O and O' are the donor atoms of the kappa(2)-carboxylate group, and the plane of the carboxyl-substituted ferrocene cyclopentadienyl is 24.93 (6)degrees.

  DOI：

  10.1107/s0108270101019370