| 318497-29-9

• CAS: 318497-29-9
• 化学式: C₃H₆O*C₁₆H₁₄Cl₂MnN₂O₂*C₁₆H₁₄N₂O₂*Cl*Mn
• 分子量: 806.914
• InChiKey: PEBVRFKTSUZYLI-AETNTUEESA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(N,N'-disalicylidenethylenediaminato)manganese(IV) complex 、 丙酮 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Structures of dichloromanganese(IV) complexes with bidentate and tetradentate Schiff base ligands

  摘要：

  The dichloromanganese(IV) complexes with various bidentate and tetradentate Schiff base ligands, Mn-IV(L'),Cl-2 and Mn-IV(L)Cl-2 have been obtained by the reactions of chloromanganese(III) complexes, Mn-III(L')(2)Cl and Mn-III(L)Cl with hydrogen chloride or by the reactions of acetatomanganese(III) complexes, Mn-III(L')(2)OAc, with chlorine as deep green crystals, where L'H denotes bidentate Schiff base ligands N-R-salH (N-alkyl-salicylideneamine) and R can be n-C3H7, n-C6H13, n-C8H17, or n-C12H25, and LH, denotes tetradentate Schiff base ligands X-salenH, (N,N'-disubstituted-salicylideneethylenediamine) or X-salpnH(2) (N,N'-disubstituted salicylidenepropanediamine) and X can be H and 5-Br. X-ray structure analysis of the present dichloromanganese(IV) complexes has revealed that two chloride ions coordinate to the central manganese ion in a trans-form. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00503-9