{ruthenium(III)(ammine)5(methylpyrazinium)}(4+) | 48135-77-9

• 英文名称: {ruthenium(III)(ammine)5(methylpyrazinium)}(4+)
• 英文别名: [Ru(NH3)5(N-methylpyrazinium)](4+)
• CAS: 48135-77-9
• 化学式: C₅H₂₂N₇Ru
• 分子量: 281.347
• InChiKey: AATYGTMQYNKNAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {ruthenium(III)(ammine)5(methylpyrazinium)}(4+) 在 三氟甲磺酸 、 lithium trifluoromethanesulfonate 、 维生素 C 作用下， 以 水 为溶剂， 生成 {ruthenium(II)(ammine)5(methylpyrazinium)}(3+)
  参考文献：
  名称：

  Akhtar, Mohammed J.; Haim, Albert, Inorganic Chemistry, 1988, vol. 27, # 9, p. 1608 - 1610

  摘要：

  DOI：
• 作为产物：
  描述：

  {ruthenium(II)(ammine)5(methylpyrazinium)}(PF6)3 在 过氧二硫酸 作用下， 生成 {ruthenium(III)(ammine)5(methylpyrazinium)}(4+)
  参考文献：
  名称：

  Akhtar, Mohammed J.; Haim, Albert, Inorganic Chemistry, 1988, vol. 27, # 9, p. 1608 - 1610

  摘要：

  DOI：

文献信息

• Effect of Second-Sphere Coordination. 4.¹ Factors Influencing the Electrochemical Behavior of Ruthenium−Ammine Complexes Caused by Second-Sphere Coordination of Crown Ethers
  作者：Isao Ando、Daisuke Ishimura、Kikujiro Ujimoto、Hirondo Kurihara

  DOI：10.1021/ic941048e

  日期：1996.1.1

  Second-sphere coordination was investigated spectrophotometrically and electrochemically with various ruthenium-ammine complexes with crown ethers in acetonitrile solution. Spectrophotometric results revealed that the acidity of the ammine ligands of the complex, which depends on the valence of the metal center, predominantly affects the second-sphere coordination of the crown ether to the ruthenium-ammine complexes. This fact explains the difference in the stoichiometry between the adducts of ruthenium(II) and ruthenium(III) complexes with 18-crown-6 ether. It was found that the number of ammine ligands, the pi-electron acceptability of ancillary ligands of the complex, and the flexibility of the crown ether ring affected the change in the redox potential of the complexes caused by second-sphere coordination of crown ethers.
• Kinetic studies of outer-sphere redox reactions of .mu.-pyrazinedecaamminediruthenium (II,II), (II,III), and (III,III)
  作者：Urs Furholz、Albert Haim

  DOI：10.1021/j100407a041

  日期：1986.7
• Fürholz, Urs; Haim, Albert, Inorganic Chemistry, 1987, vol. 26, # 20, p. 3243 - 3248
  作者：Fürholz, Urs、Haim, Albert

  DOI：——

  日期：——