Mn3(1,10-phenantralene)2(3,4,5-trimethoxybenzoic acid(-H))6 | 1308736-88-0

• 英文名称: Mn3(1,10-phenantralene)2(3,4,5-trimethoxybenzoic acid(-H))6
• CAS: 1308736-88-0
• 化学式: C₈₄H₈₂Mn₃N₄O₃₀
• 分子量: 1792.4
• InChiKey: DLULNCLQIPEVDP-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Mn3(1,10-phenantralene)2(3,4,5-trimethoxybenzoic acid(-H))6 以 neat (no solvent, solid phase) 为溶剂， 生成 manganese(III) oxide
  参考文献：
  名称：

  Hydrothermal synthesis, crystal structure, and thermal analysis of a Novel trinuclear manganese complex: Mn3(C12H8N2)2(C10H11O5)6

  摘要：

  A novel trinuclear manganese(II) complex, Mn-3(C12H8N2)(2)(C10H11O5)(6) (I), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P2(1)/n, with cell parameters a = 12.1935(7), b = 19.0249(11), c = 18.0515(10) angstrom, beta = 105.0430(10)degrees, V = 4044.1(4) angstrom(3), Z = 2. Two of the three manganese atoms in the crystal structure are crystallographically equivalent and adopt N2O4 coordination mode, whereas the remaining manganese atom adopts O-6 coordination mode, which forms a nearly regular octahedron. The experimental result of thermal analysis shows that complex I remains stable below 300 degrees C.

  DOI：

  10.1134/s1070328411040129
• 作为产物：
  描述：

  1,10-菲罗啉 、 manganese(II) chloride tetrahydrate 、 3,4,5-三甲氧基苯甲酸 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成 Mn3(1,10-phenantralene)2(3,4,5-trimethoxybenzoic acid(-H))6
  参考文献：
  名称：

  Hydrothermal synthesis, crystal structure, and thermal analysis of a Novel trinuclear manganese complex: Mn3(C12H8N2)2(C10H11O5)6

  摘要：

  A novel trinuclear manganese(II) complex, Mn-3(C12H8N2)(2)(C10H11O5)(6) (I), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P2(1)/n, with cell parameters a = 12.1935(7), b = 19.0249(11), c = 18.0515(10) angstrom, beta = 105.0430(10)degrees, V = 4044.1(4) angstrom(3), Z = 2. Two of the three manganese atoms in the crystal structure are crystallographically equivalent and adopt N2O4 coordination mode, whereas the remaining manganese atom adopts O-6 coordination mode, which forms a nearly regular octahedron. The experimental result of thermal analysis shows that complex I remains stable below 300 degrees C.

  DOI：

  10.1134/s1070328411040129