7,9-Ph2-nido-7,9-P2B9H9 | 620170-81-2

• 英文名称: 7,9-Ph2-nido-7,9-P2B9H9
• CAS: 620170-81-2
• 化学式: C₁₂H₁₉B₉P₂
• 分子量: 322.529
• InChiKey: UQBAHDUULAZHRW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  苯基二氯化磷 、 (CH3)4N[nido-B9H12] 在 NaH 作用下， 以 乙二醇二甲醚 为溶剂， 以20%的产率得到7,9-Ph2-nido-7,9-P2B9H9
  参考文献：
  名称：

  Synthesis and structural characterization of an 11-vertex nido-diphosphaborane, 7,9-Ph2-nido-7,9-P2B9H9

  摘要：

  The new 11-vertex nido-diphosphaborane, 7,9-Ph-2-nido-7,9-P2B9H9, has been synthesized by the reaction of Me4N+ [nido-B9H12-] with PhPCl2 in the presence of NaH. A single crystal X-ray diffraction determination and DFT/GIAO/NMR methods have both established that the compound has an open cage structure containing the phosphorus atoms in non-adjacent positions oil the open face. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00165-7