[(9-([N-n-propyl-N-(diphenylphosphino)amino]methyl)anthracene)Au]ClO4 | 882041-24-9

• 英文名称: [(9-([N-n-propyl-N-(diphenylphosphino)amino]methyl)anthracene)Au]ClO4
• CAS: 882041-24-9
• 化学式: C₃₀H₂₈AuNP*ClO₄
• 分子量: 729.95
• InChiKey: VJEMAUUEUZLEQZ-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  [(9-([N-n-propyl-N-(diphenylphosphino)amino]methyl)anthracene)Au]ClO4 、 三苯基膦 以 二氯甲烷 为溶剂， 生成 [(9-([N-n-propyl-N-(diphenylphosphino)amino]methyl)anthracene)Au(PPh3)]ClO4
  参考文献：
  名称：

  Gold(I) η²-Arene Complexes

  摘要：

  The reaction of 9-{[N-n-propyl-N-(diphenylphosphino)amino]methyl}anthracene (1) with Au(SMe2)Cl yields complex 2 with an arm-opening configuration. The latter is treated with AgClO4 to form complex 4 and then respectively reacted with acetonitrile, pyridine, and triphenylphosphine sulfide to afford novel gold(l) eta(2)-arene complexes 3a-c, which have arm-closing configurations and feeble or weak fluorescence emissions. The observation can be attributed to charge transfer from the anthracene unit to the Au+ ion. When the solution of 3a or 4 in CH2Cl2 was added with 1 equiv of Ph3P, complex 5 with the arm-opening configuration was formed and strong emission was restored.

  DOI：

  10.1021/ic051869r
• 作为产物：
  描述：

  9-([N-n-propyl-N-(diphenylphospino)amino]methyl)anthracene 以 二氯甲烷 为溶剂， 生成 [(9-([N-n-propyl-N-(diphenylphosphino)amino]methyl)anthracene)Au]ClO4
  参考文献：
  名称：

  Gold(I) η²-Arene Complexes

  摘要：

  The reaction of 9-{[N-n-propyl-N-(diphenylphosphino)amino]methyl}anthracene (1) with Au(SMe2)Cl yields complex 2 with an arm-opening configuration. The latter is treated with AgClO4 to form complex 4 and then respectively reacted with acetonitrile, pyridine, and triphenylphosphine sulfide to afford novel gold(l) eta(2)-arene complexes 3a-c, which have arm-closing configurations and feeble or weak fluorescence emissions. The observation can be attributed to charge transfer from the anthracene unit to the Au+ ion. When the solution of 3a or 4 in CH2Cl2 was added with 1 equiv of Ph3P, complex 5 with the arm-opening configuration was formed and strong emission was restored.

  DOI：

  10.1021/ic051869r