di-μ-chloro-2:3κ4-Cl-dichloro-2κCl,3κCl-bis[μ-2,2'-[1,4-butanediylbis(nitromethylidene)]diphenolato]-1:2κ6-O,N,N',O':O,O';3,4κ6-O,O':O,N,N',O'-dicopper(II)dimercury(II) | 428913-30-8

• 英文名称: di-μ-chloro-2:3κ4-Cl-dichloro-2κCl,3κCl-bis[μ-2,2'-[1,4-butanediylbis(nitromethylidene)]diphenolato]-1:2κ6-O,N,N',O':O,O';3,4κ6-O,O':O,N,N',O'-dicopper(II)dimercury(II)
• 英文别名: bis[[μ-N,N'-bis(salicylidene)-1,4-butanediamine-N,N',O,O'-copper(II)]-μchloro-chloromercury(II)]
• CAS: 428913-30-8
• 化学式: C₃₆H₃₆Cl₄Cu₂Hg₂N₄O₄
• 分子量: 1258.79
• InChiKey: SRAMILVOYLLANU-BNOPRINQSA-F

反应信息

• 作为产物：
  描述：

  N,N'-tetramethylene-bis(salicylaldiminato)copper(II) 、 mercury dichloride 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 为溶剂， 生成 di-μ-chloro-2:3κ4-Cl-dichloro-2κCl,3κCl-bis[μ-2,2'-[1,4-butanediylbis(nitromethylidene)]diphenolato]-1:2κ6-O,N,N',O':O,O';3,4κ6-O,O':O,N,N',O'-dicopper(II)dimercury(II)
  参考文献：
  名称：

  Bis{[μ-N,N′-bis(salicylidene)-1,4-butanediamine-N,N′,O,O′-copper(II)]-μ-chloro-chloromercury(II)}

  摘要：

  A new tetranuclear Cu-II-Hg-II-Hg-II-Cu-II complex, [Cu2Hg2Cl4-(C18H18N2O2)(2)], has been prepared by means of a copper complex found in the literature. The molecular structure of this complex was determined by X-ray diffraction and the Cu-Hg-Hg-Cu chain was seen to be non-linear. The change in magnetic susceptibility with temperature was recorded for this complex and observed to abide by the Curie-Weiss law. The coordination around the Hg-II ions is square pyramidal. The Cu...Hg bridging distance is 3.5269 (7) Angstrom.

  DOI：

  10.1107/s0108270101019709