{(tri-n-butylphosphine)dicarbonyl(η6-1,4-bis(tri-n-butylstannyl)benzene)chromium} | 140864-38-6

• 英文名称: {(tri-n-butylphosphine)dicarbonyl(η6-1,4-bis(tri-n-butylstannyl)benzene)chromium}
• CAS: 140864-38-6
• 化学式: C₄₄H₈₅CrO₂PSn₂
• 分子量: 966.547
• InChiKey: DAZBYYIAOUBONV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  {(tri-n-butylphosphine)dicarbonyl(η6-1,4-bis(tri-n-butylstannyl)benzene)chromium} 、 二苯基氯化膦 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到{(tri-n-butylphosphine)dicarbonyl(η6-1,4-(Ph2P)2benzene)chromium}
  参考文献：
  名称：

  Synthesis of the new metalloligands [η6-(PPh2)xC6H6−x]Cr(CO)2(L) [x = 1,2; L = CO and PR3] and some rhodium(I) complexes

  摘要：

  Transmetallation of {eta(6)-1,4-(Bun3Sn)2C6H4}Cr(CO)2(PBun3) with nBuLi followed by treatment with diphenylchlorophosphine afforded as the major product {eta(6)-1,4-(PPh2)2C6H4}Cr(CO)2(PBun3) (4) and a minor amount of {eta(6)-1-(SnBun3)-4-(PPh2)C6H4}Cr(CO)2(PBun3) (5). Treatment of {eta(6)-1,4-(PPh2)2C6H4}Cr(CO)2(L) (9, L = CO; 4, L = PBun3) with [(CO)2RhCl]2 liberated carbon monoxide and gave the heterobimetallic coordination polymers {[eta(6)-1,4-(PPh)2C6H4]Cr(CO)2L]Rh(CO)Cl}n (10a, L = CO; 10b, L = PBun3). Coordination of both PPh2 substituents to rhodium led to hindered rotation about the Cr-(eta(6)-arene) axis (DELTA-G double-ended dagger = 11.7 +/- 0.1 kcal mol-1 for 10b, estimated from the P-31 DNMR spectra). The transmetallation chemistry was also used to prepare {eta(6)-(PPh2)C6H5}Cr(CO)2(L) (8a, L = CO; 8b, L = PPh3] in excellent yields.

  DOI：

  10.1016/s0277-5387(00)83176-9
• 作为产物：
  描述：

  {η6-1,4-bis(tri-n-butylstannyl)benzene}chromium tricarbonyl 、 三丁基膦 以 苯 为溶剂， 以86%的产率得到{(tri-n-butylphosphine)dicarbonyl(η6-1,4-bis(tri-n-butylstannyl)benzene)chromium}
  参考文献：
  名称：

  Synthesis of the new metalloligands [η6-(PPh2)xC6H6−x]Cr(CO)2(L) [x = 1,2; L = CO and PR3] and some rhodium(I) complexes

  摘要：

  Transmetallation of {eta(6)-1,4-(Bun3Sn)2C6H4}Cr(CO)2(PBun3) with nBuLi followed by treatment with diphenylchlorophosphine afforded as the major product {eta(6)-1,4-(PPh2)2C6H4}Cr(CO)2(PBun3) (4) and a minor amount of {eta(6)-1-(SnBun3)-4-(PPh2)C6H4}Cr(CO)2(PBun3) (5). Treatment of {eta(6)-1,4-(PPh2)2C6H4}Cr(CO)2(L) (9, L = CO; 4, L = PBun3) with [(CO)2RhCl]2 liberated carbon monoxide and gave the heterobimetallic coordination polymers {[eta(6)-1,4-(PPh)2C6H4]Cr(CO)2L]Rh(CO)Cl}n (10a, L = CO; 10b, L = PBun3). Coordination of both PPh2 substituents to rhodium led to hindered rotation about the Cr-(eta(6)-arene) axis (DELTA-G double-ended dagger = 11.7 +/- 0.1 kcal mol-1 for 10b, estimated from the P-31 DNMR spectra). The transmetallation chemistry was also used to prepare {eta(6)-(PPh2)C6H5}Cr(CO)2(L) (8a, L = CO; 8b, L = PPh3] in excellent yields.

  DOI：

  10.1016/s0277-5387(00)83176-9