[(η6-cymene)RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)2](1+) | 788822-02-6

• 英文名称: [(η6-cymene)RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)2](1+)
• 英文别名: [η6-cymene)RuH(pta)2](1+)
• CAS: 788822-02-6
• 化学式: C₂₂H₃₉N₆P₂Ru
• 分子量: 550.609
• InChiKey: BDTKNZWRJGLUGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯(p-甲基异丙苯)钌(II) 二聚体 、 氢气 、 1,3,5-三氮杂-7-磷杂金刚烷 以 水 为溶剂， 生成 [(η6-cymene)RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)2](1+)
  参考文献：
  名称：

  Water-soluble (η6-arene)ruthenium(II)-phosphine complexes and their catalytic activity in the hydrogenation of bicarbonate in aqueous solution

  摘要：

  The reactions of [(eta(6)-C6H6)RuCl2](2) and [(eta(6)-p-cymene)RuCl2](2) With hydrogen in the presence of the water-soluble phosphines tppts (meta-trisulfonated triphenylphosphine) and pta (1,3,5-triaza-7-phosphaadamantane) afforded as the main species [(eta(6)- C6H6)RuH(tppts)(2)](+), [(eta(6)-C6H6)RuH(pta)(2)](+), [(eta(6)-p-cymene)RuH(tppts)(2)](+) and [(eta(6)-p-cymene)RuH(pta)(2)](+). This latter complex was also formed in the reaction of [(eta(6)-p-cymene)RuCl2(pta)] and hydrogen with a redistribution of pta. In addition, prolonged hydrogenation at elevated temperatures and in the presence of excess of pta led to the formation of the arene-free [RuH(pta)(4)CI], [RuH(pta)(4)(H2O)](+), [RuH2(pta)(4)] and [RuH(pta)(5)](+) complexes. Ru-hydrides, such as [(eta6-arene)RuH(L)(2)](+), catalyzed the hydrogenation of bicarbonate to formate in aqueous solutions at p(H-2) = 100 bar, T = 50-70 degreesC. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.11.036