bis(tetrafluorobenzo{5,6}bicyclo{2.2.2}octa-2,5,7-triene)(3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazol-1-yl)dirhodium(I)BF4 | 136221-45-9

• 英文名称: bis(tetrafluorobenzo{5,6}bicyclo{2.2.2}octa-2,5,7-triene)(3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazol-1-yl)dirhodium(I)BF4
• CAS: 136221-45-9
• 化学式: BF₄*C₃₆H₂₅F₈N₆Rh₂
• 分子量: 986.238
• InChiKey: HBAWXNWVJOSFOH-IBGYCRMISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氟硼酸钠 、 [Rh2(μ-Cl)2(tetrafluorobenzobarrelene)2] 、 3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazole 在 KOH 作用下， 以 甲醇 、 丙酮 为溶剂， 以78%的产率得到bis(tetrafluorobenzo{5,6}bicyclo{2.2.2}octa-2,5,7-triene)(3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazol-1-yl)dirhodium(I)BF4
  参考文献：
  名称：

  Rhodium(I) complexes with the polydentate ligand 3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazole

  摘要：

  The behaviour towards Rh(I) of a new ligand containing three linked pyrazoles (HLL) has been studied. Depending on which diolefin, COD or TFB, is used, mono or dinuclear complexes are obtained. The structures of the four complexes, [RhCl(COD)(HLL)], [{RhCl(TFB)}2(mu-HLL)], [Rh(LL)(COD)] and [{Rh(TFB)}2(mu-LL)]BF4, have been established by H-1 and C-13 NMR spectroscopy. In most cases, the NMR spectra reveal fluxional processes involving not only the Rh(I) metal but also the N-H proton and the diolefin.

  DOI：

  10.1016/0022-328x(91)86061-t