| 132774-51-7

• CAS: 132774-51-7
• 化学式: C₁₈H₂₃Ti*ClO₄
• 分子量: 386.711
• InChiKey: CDLPLUSAZLFSDA-HTQGOHFJSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η5-C5Me5)Ti(η8-C8H8) 、 四丁基高氯酸铵 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  钛夹心复合物（Cp）Ti（L）和（Cp *）Ti（L）的电化学和光谱电化学性质，其中L为环辛酸酯（C8H8）或对yl离子（C7H7 +）

  摘要：

  Electrochemical and spectroelectrochemical data for (Cp)Ti(L) and (Cp*)Ti(L), where Cp is the anion of cyclopentadienyl and Cp* is the anion of pentamethylcyclopentadienyl and L is either cyclooctatetraene (C8H8) or the tropylium ion (C7H7+) are presented in this paper. The electrochemical properties of complexes 1-4 [(Cp)Ti(L) L = C8H8 (1), C7H7 (2); (Cp*)Ti(L), L = C8H8 (3), C7H7 (4)] are shown to be dependent upon the electron-donating ability of L and the solvent-supporting electrolyte system. Complexes 2 and 4 can be reduced and oxidized by one electron, while complexes 1 and 3 only exhibit a one-electron oxidation. The presence of perchlorate anion, from the supporting electrolyte, strongly affects the electrochemical response for complexes 1 and 3 but not complexes 2 and 4. The synthesis of (Cp*)Ti(C8H8)(ClO4) is described, and this species is characterized by H-1 NMR, infrared, and electronic spectra and by electrochemical methods. An electron-transfer mechanism for complexes 1-4 is presented, and the use of spectroelectrochemical methods to examine the site of electron transfer for this set of organometallic species is discussed.

  DOI：

  10.1021/om00051a009