[5,15-bis(pentafluorophenyl)-10,20-bis(4-ethynylphenyl)porphyrinato]aluminum(III)methoxide | 1448874-86-9

• 英文名称: [5,15-bis(pentafluorophenyl)-10,20-bis(4-ethynylphenyl)porphyrinato]aluminum(III)methoxide
• CAS: 1448874-86-9
• 化学式: C₄₉H₂₁AlF₁₀N₄O
• 分子量: 898.698
• InChiKey: KISBPWJMIALZCF-POENIERRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [5,15-bis(pentafluorophenyl)-10,20-bis(4-ethynylphenyl)porphyrinato]aluminum(III)methoxide 、 3,5-二叔丁基苯甲酸 以 二氯甲烷 为溶剂， 反应 12.0h， 以87%的产率得到[5,15-bis(pentafluorophenyl)-10,20-bis(4-ethynylphenyl)porphyrinato]aluminum(III)(3,5-di-tert-butyl benzoate)
  参考文献：
  名称：

  Enhanced Catalytic Activity through the Tuning of Micropore Environment and Supercritical CO₂ Processing: Al(Porphyrin)-Based Porous Organic Polymers for the Degradation of a Nerve Agent Simulant

  摘要：

  An Al(porphyrin) functionalized with a large axial ligand was incorporated into a porous organic polymer (POP) using a cobalt-catalyzed acetylene trimerization strategy. Removal of the axial ligand afforded a microporous POP that is catalytically active in the methanolysis of a nerve agent simulant. Supercritical CO2 processing of the POP dramatically increased the pore size and volume, allowing for significantly higher catalytic activities.

  DOI：

  10.1021/ja405495u
• 作为产物：
  描述：

  5,15-bis(pentafluorophenyl)-10,20-bis(4-ethynylphenyl)porphyrin 、 甲醇 、 三甲基铝 以 正庚烷 、 二氯甲烷 为溶剂， 反应 0.5h， 以92%的产率得到[5,15-bis(pentafluorophenyl)-10,20-bis(4-ethynylphenyl)porphyrinato]aluminum(III)methoxide
  参考文献：
  名称：

  Enhanced Catalytic Activity through the Tuning of Micropore Environment and Supercritical CO₂ Processing: Al(Porphyrin)-Based Porous Organic Polymers for the Degradation of a Nerve Agent Simulant

  摘要：

  An Al(porphyrin) functionalized with a large axial ligand was incorporated into a porous organic polymer (POP) using a cobalt-catalyzed acetylene trimerization strategy. Removal of the axial ligand afforded a microporous POP that is catalytically active in the methanolysis of a nerve agent simulant. Supercritical CO2 processing of the POP dramatically increased the pore size and volume, allowing for significantly higher catalytic activities.

  DOI：

  10.1021/ja405495u