| 561001-30-7

• CAS: 561001-30-7
• 化学式: C₂₇H₃₆N₄Ni₂O₅S₂
• 分子量: 678.119
• InChiKey: QUGSLIPWFQEARR-WBIAXQAASA-K

反应信息

• 作为产物：
  描述：

  2-([(3-dimethylaminopropyl)methylamino]methyl)-4-methyl-6-[(2-methylsulfanylphenylimino)methyl]phenol 、 sodium thiocyanide 、 nickel(II) acetate tetrahydrate 以 甲醇 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Oligonuclear nickel(II) complexes of asymmetric compartmental ligands bearing adjacent {N2O} and {N,S,O} donor sets

  摘要：

  Asymmetric compartmental proligands bearing adjacent {N2O} and {NSO} donor sets have been prepared and used in complexation reactions with nickel(II). [4-Methyl-2-{[methyl-(2-pyridin-2-yl-ethyl)amino]methyl}-6-[(2-methylsulfanyl phenyl imino)methyl]phenol (HL3) and 2-{[(3-dimethylamino-propyl)methylamino]methyl}-4-methyl-6-[(2-methylsulfanylphenyl imino)methyl]phenol (HL4) gave the dinuclear nickel(II) complexes, [Ni-2(L-3)(AcO)(NCS)(2)(CH3CN)] (3), Ni-2(L-4)(AcO)(2)(NCS)] (4), whereas 4-methyl-2-{[methyl(2-pyridin-2-yl-ethyl)amino]-methyl}-6-[(2-methylsulfanylethylimino)-methyl]-phenol (HL5) and 4-methyl-2-{[methyl(2-pyridin-2-yl-ethyl)amino]methyl}-6-[(3-methylsulfanylpropylimino) methyl]-phenol (HL6), gave the trinuclear nickel(II) complexes [Ni-3(L-5)(2)(OAc)(2)(NCS)(2)].2H(2)O (5) and [Ni-3(L-6)(2)(OAc)(2)(NCS)(2)].MeOH (6). The crystal structures of 3-6 are reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01386-5