1,4-[RuCl(CO)(PMe3)3CH=CH]2C6H3F | 1146301-54-3

• 英文名称: 1,4-[RuCl(CO)(PMe3)3CH=CH]2C6H3F
• CAS: 1146301-54-3
• 化学式: C₃₀H₆₁Cl₂FO₂P₆Ru₂
• 分子量: 931.7
• InChiKey: CVTBNTJIKIKSRV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 1,4-二乙炔基-2-氟苯 以 四氢呋喃 、 二氯甲烷 为溶剂， 以74%的产率得到1,4-[RuCl(CO)(PMe3)3CH=CH]2C6H3F
  参考文献：
  名称：

  Synthesis, Characterization, and Substituent Effects of Binuclear Ruthenium Vinyl Complexes [RuCl(CO)(PMe₃)₃]₂(μ-CH═CH−Ar−CH═CH)

  摘要：

  A series of binuclear ruthenium vinyl complexes [RuCl(CO)(PMe3)(3)](2)(mu-CH=CH-Ar-CH=CH) (Ar = C6H4 (6a), C6H3CH3 (6b), C6H3OCH3 (6c), C6H3F (6d), C6H3Cl (6e), C6H3Br (6f), C6H3CN (6g), C6H3NO2 (6h), C6H2(CH3)(2)-2,5 (6i), C6H2(OCH3)(2)-2,5 (6i), C6H2(F)(2)-2,5 (6k), C6H2(CF3)(2)-2,5 (6l), and C6H3CF3 (6m)) have been prepared. The respective products have been characterized by elemental analyses, NMR spectrometry, and UV/vis spectrophotometry. The structures of 6h, 6i, and 6j have been established by X-ray crystallography. Electrochemical studies have revealed that intermetallic electron communication between the two Ru centers may be fine-tuned by modification of the bridging spacers, that is, by introducing one or two substituent groups on the 1,4-diethenylphenylene bridge. Electron-releasing substituents have been found to facilitate electron communication between the two metal centers.

  DOI：

  10.1021/om900018y