dicarba[2]cobaltocenophane | 1019652-37-9

• 英文名称: dicarba[2]cobaltocenophane
• 英文别名: [Co(η5-C5H4)2(CH2)2]
• CAS: 1019652-37-9
• 化学式: C₁₂H₁₂Co
• 分子量: 215.22
• InChiKey: SYRLZGYWTHUSGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dicarba[2]cobaltocenophane 、 sodium palmitoylalaninate 在 氧气 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 24.0h， 生成 [dicarba[2]cobaltocenophane][N-palmitoyl-L-alanine]_n
  参考文献：
  名称：

  使用阴离子表面活性剂在多个长度尺度上向阳离子聚钴茂的手性传输

  摘要：

  手性聚合物在自然界中无处不在，手性材料的自组装是一个广泛关注的领域。在本文中，我们描述了基于聚（cobaltoceniumethylene）（[PCE] n+）的手性金属聚合物的形成，该聚合物是通过在对映纯 N-酰基氨基酸存在下氧化聚（cobaltocenylethylene）（PCE）制备的-衍生的阴离子表面活性剂，例如 N-棕榈酰-l-丙氨酸 (C16-l-Ala) 和 N-棕榈酰-d-丙氨酸 (C16-d-Ala)。据推测，所得金属聚合物配合物 [PCE][C16-l/d-Ala] n 包含紧密的离子接触，并通过轴向手性烯属 CH2-CH2 桥显示手性，导致发色 [CoCp2]+ 单元的相互作用通过手征空间。长棕榈酰 (C16) 表面活性剂尾部的空间影响是将手性传递给聚合物的关键，并导致刷状两亲性大分子结构，该结构还提供在极性有机溶剂（例如 EtOH、THF）中的溶解度。将这些溶液透

  DOI：

  10.1021/jacs.8b03112
• 作为产物：
  描述：

  、 cobalt(II) chloride 以 四氢呋喃 为溶剂， 以9%的产率得到dicarba[2]cobaltocenophane
  参考文献：
  名称：

  Synthesis and Structures of Strained, Neutral [d⁷] and Cationic [d⁶] Hydrocarbon-Bridged [n]Cobaltocenophanes (n = 2, 3)

  摘要：

  The first neutral and paramagnetic [n]cobaltocenophanes Co(eta(5)-C5H4)(2)(CH2)(2) (5) and Co(eta(5)-C5H4)(2)(CH2)(3) (6) with sterically undemanding hydrocarbon bridges were prepared by the reaction of CoCl2 with the corresponding ligand precursor (LiC5H4)(2)(CH2)(n) (n = 2 for 5; n = 3 for 6) in THF. In order to analyze the ring strain present, the molecular structures of 5 and 6 were determined using single-crystal X-ray diffraction. The neutral, paramagnetic 19-valence-electron [2]cobaltocenophane 5 is substantially distorted from metallocene-type geometry (tilt angle alpha: 27.1(4)degrees) and therefore highly strained, whereas [3]cobaltocenophane 6 is only moderately distorted (alpha: 12.0(11)degrees). Both 5 and 6 were readily oxidized with NH4Cl in the presence of atmospheric oxygen to form the corresponding cationic [n]cobaltocenophane salts [Co(eta(5)-C5H4)(2)(CH2)(n)(+)][A(-)] 7 and 8 (n = 2) and 9 (n = 3). Compound 7 (A = Cl) was isolated by means of extraction into CH2Cl2, whereas 8 and 9 were isolated by phase precipitation from aqueous solutions of NaPF6. The X-ray analysis for cationic, diamagnetic, 18-valence-electron [2]cobaltoceniumphane 7 revealed substantially less distortion from metallocene-type geometry (tilt-angle alpha: 21.4(2)degrees) compared to paramagnetic 19-valence-electron compound 5. In order to examine the electronic structures of 5, 6, 8, and 9, solution UV-vis spectra were recorded, and these reflected the increasing distortion as a result of the introduction of progressively shorter ansa-bridges. Cyclic voltammetric analysis of 8 and 9 in CH2Cl2 revealed that each cobaltoceniumphane exhibits a one-electron reduction, whereby redox potentials E degrees appeared to vary as a function of the tilt angle.

  DOI：

  10.1021/om700941v

文献信息

• Main-Chain Heterobimetallic Block Copolymers: Synthesis and Self-Assembly of Polyferrocenylsilane-b-Poly(cobaltoceniumethylene)
  作者：Joe B. Gilroy、Sanjib K. Patra、John M. Mitchels、Mitchell A. Winnik、Ian Manners

  DOI：10.1002/anie.201008184

  日期：2011.6.20

  Main‐chain heterometallic block copolymers composed of iron‐ and cobalt‐rich blocks (see picture) were synthesized through consecutive photocontrolled ring‐opening polymerization (ROP) of sila[1]ferrocenophanes and dicarba[2]cobaltocenophanes followed by oxidation of the cobaltocene‐containing block. The redox properties and self‐assembly of the resulting block copolymers in solution were also studied

  两种金属胜过一种金属：通过连续的sila [1]二茂铁基戊二烯和dicarba [2]钴十一碳烷烃的光控开环聚合（ROP）合成了由富含铁和钴的嵌段组成的主链杂金属嵌段共聚物（见图）。然后氧化含钴茂的嵌段。还研究了所得嵌段共聚物在溶液中的氧化还原性能和自组装性。
• Ring-Opening Polymerization of 19-Electron [2]Cobaltocenophanes: A Route to High-Molecular-Weight, Water-Soluble Polycobaltocenium Polyelectrolytes
  作者：Ulrich F. J. Mayer、Joe B. Gilroy、Dermot O’Hare、Ian Manners

  DOI：10.1021/ja903513e

  日期：2009.8.5

  Water-soluble, high-molecular-weight polycobaltocenium polyelectrolytes have been prepared by ring-opening polymerization (ROP) techniques. Anionic polymerization of a strained 19-electron dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium chloride resulted in the formation of oligomers with up to nine repeat units. Thermal ROP of dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium nitrate resulted in the formation of high-molecular-weight polycobaltocenium nitrate, a redox-active cobalt-containing polyelectrolyte.