| 939775-83-4

• CAS: 939775-83-4
• 化学式: C₃₄H₁₈Cl₆N₂O₂Ti
• 分子量: 747.127
• InChiKey: WIJVSFIYYSVIKM-YESWJRNQSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-bis(3,5-dichloro-2-hydroxybenzylideneamino)-1,1'-binaphthyl 、 四氯化钛 以 四氢呋喃 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Polymerization of ethylene and propene promoted by binaphthyl-bridged Schiff base complexes of titanium

  摘要：

  Three new binaphthyl-bridged Schiff base complexes featuring different phenolate substituents (meta-Me, orthopara-di-Cl, orthopara-di-Br) were synthesized. H-1 and C-13 NMR analyses indicated that the cis-beta isomers are preferentially formed in any case. These complexes were tested as precatalysts for ethylene and propene polymerization comparing their behaviour to that of related titanium and zirconium complexes previously reported.The beneficial effect on polymerization activity of halogen atoms in the ortho, para positions of the phenolate rings was also demonstrated. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.05.046