[Zr(NMe2)3Sr(μ-O)(CH(CMeN(2,6-iPr2C6H3))2)]2 | 1035421-08-9

• 英文名称: [Zr(NMe2)3Sr(μ-O)(CH(CMeN(2,6-iPr2C6H3))2)]2
• CAS: 1035421-08-9
• 化学式: C₇₀H₁₁₈N₁₀O₂Sr₂Zr₂
• 分子量: 1489.46
• InChiKey: DIJDCIWHKHTMCA-VMFDZVMKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四(二甲氨基)锆 、 [Sr2(thf)3(μ-OH)2(CH(CMeN(2,6-iPr2C6H3))2)2] 以 甲苯 为溶剂， 以69.1%的产率得到[Zr(NMe2)3Sr(μ-O)(CH(CMeN(2,6-iPr2C6H3))2)]2
  参考文献：
  名称：

  A Reactivity Change of a Strontium Monohydroxide by Umpolung to an Acid

  摘要：

  Controlled hydrolysis of strontium amide LSN(SiMe3)(2)(thf) (L = CH(CMe2,6-i-Pr2C6H3N)(2)) (1) gave an unprecedented example of a hydrocarbon-soluble strontium hydroxide, [LSr(thf)(mu-OH)(2)Sr(thf)(2)L] (2). In compound 2, the tetrahydrofuran (THF) molecules can easily replaced by benzophenone and triphenylphosphine oxide to yield [LSr(mu-OH)(OCPh2)](2) (3) and [LSr(mu-OH)(OPPh3)](2) (4) compounds. Among the two strontium atoms of 2, one is coordinated to a single THF molecule, while the other is coordinated to two THF molecules. Interestingly, strontium hydroxide complex 2 behaves as an acid in its reaction with Zr(NMe2)(4) and results in a heterobimetallic oxide, [LSr(mu-O)Zr(NMe2)(3)](2) (5). Compound 5 is dimeric in the solid state and contains a Sr2Zr2O2 core.

  DOI：

  10.1021/ic800284u