| 172299-98-8

• CAS: 172299-98-8
• 化学式: C₂₆H₅₉Cl₃P₂Pd₂Se
• 分子量: 831.861
• InChiKey: UTODDUUTKLGOOR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Pd2Cl2(μ-Cl)2(PBu3)2] 、 sodium ethylselenolate 以 甲醇 、 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Binuclear complexes of palladium(II) and platinum(II) containing bridging ethylselenolato group: X-ray crystal structure of [Pt2Cl2(μ-SeEt)2(PEt3)2]

  摘要：

  The reaction of [M(2)Cl(2)(mu-Cl)(2)(PR(3))(2)] with NaSeEt in 1 : 1 and 1 : 2 stoichiometry gave [M(2)Cl(2)(mu-Cl)(mu-SeEt)(PR(3))(2)] and [M(2)Cl(2)(mu-SeEt)(2)(PR(3))(2)] (M = Pd or Pt; PR(3) = PEt(3), PBu(3), PMe(2)Ph or PMePh(2)), respectively. These complexes were characterized by elemental analysis and NMR data (H-1 and P-31). The mixed chloro/ethylselenolato bridged complexes adopt a cis configuration with phosphine trans to the bridging chloride. The molecular structure of [Pt2Cl2(mu-SeEt)(2)(PEt(3))2] has been determined by single crystal X-ray diffraction. The complex has a planar four-membered ''Pt2Se2'' bridge.

  DOI：

  10.1016/0277-5387(95)00155-l