| 436808-47-8

• CAS: 436808-47-8
• 化学式: C₃₂H₄₆N₂Ni
• 分子量: 517.421
• InChiKey: MRTFCPBMNRLXGY-WYXAPHMCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 tris(pentafluorophenyl) aluminum 以 not given 为溶剂， 生成
  参考文献：
  名称：

  α-Iminoenamido Ligands:  A Novel Structure for Transition-Metal Activation

  摘要：

  This communication shows that it is possible to activate nickel complexes containing the alpha-iminoenamide ligand using B(C6F5)(3) or AI(C6F5)(3) to generate catalysts that polymerize ethylene. The polymerization of ethylene using these novel compounds is discussed. The novel activation method is confirmed by the X-ray crystallography studies of the methallyl analogs.

  DOI：

  10.1021/om020251b
• 作为产物：
  描述：

  [(C4H7)NiCl]2 、 potassium N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)-1-methylenepropylamide 以 not given 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  α-Iminoenamido Ligands:  A Novel Structure for Transition-Metal Activation

  摘要：

  This communication shows that it is possible to activate nickel complexes containing the alpha-iminoenamide ligand using B(C6F5)(3) or AI(C6F5)(3) to generate catalysts that polymerize ethylene. The polymerization of ethylene using these novel compounds is discussed. The novel activation method is confirmed by the X-ray crystallography studies of the methallyl analogs.

  DOI：

  10.1021/om020251b