| 33031-12-8

• CAS: 33031-12-8
• 化学式: C₃₆H₃₀NP₂*Cl₃Hg
• 分子量: 845.537
• InChiKey: NUQKHRKQPLVFDB-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  、 (1,4-dioxane-2,3-diyldithio)ethylenedithiotetrathiafulvalene 、 mercury dichloride 以 乙醇 、 氯苯 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  The structures of organic metals (DOET)(4)[Hg2Cl6] (1) and (DOET)(4)[Hg2Br6] (2), where DOET is (1,4-dioxanediyl-2,3-dithio)ethylenedithiotetrathiafulvalene, were established by X-ray diffraction analysis. Compounds 1 and 2 are isostructural, and their crystals have layered structures. The conducting layers formed by the stacked DOET1/2+ cations alternate with the layers of the [Hg2X6](2-) anions (X = Cl, Br). The temperature dependence of the conductivity of salt 1 shows a metallic character in the range of 300-4 K. Compound 2 undergoes the metal-semiconductor phase transition (TM-1) at 100 K.

  DOI：

  10.1023/a:1023406832130