tris(1,2-N,N-dimethylaminomethylferrocenyl)stibine | 1085319-16-9

• 英文名称: tris(1,2-N,N-dimethylaminomethylferrocenyl)stibine
• CAS: 1085319-16-9
• 化学式: C₃₉H₄₈Fe₃N₃Sb
• 分子量: 848.121
• InChiKey: JKFQXJLEBCRHKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 tris(1,2-N,N-dimethylaminomethylferrocenyl)stibine 以 丙酮 为溶剂， 以40%的产率得到[cis-dichloro [(tris(1,2-N,N-dimethylaminomethylferrocenyl)stibino-N,Sb)]platinum(II)]*CHCl3
  参考文献：
  名称：

  Tris-(1,2-N,N-dimethylaminomethylferrocenyl)stibine and its heterotrimetallic complex

  摘要：

  New tertiary chloro-bis(1,2-N, N-dimethylaminomethylferrocenyl)stibine (1) and tris-(1,2-N, N-dimethylaminomethylferrocenyl) stibine ligand (2) containing CH2NMe2 pendenant arm at the ortho-position have been synthesized. Stibine (2) reacts with PtCl42 and hetero trimetallic cis-PtCl2L (3) complex is obtained, where stibine (2) acts as a bidentate ligand. All these compounds were characterized by various physicochemical methods and their molecular structures were determined by X-ray diffraction analyses. It is to be noted that tris(1,2-aminomethylferrocenyl) stibine represents the first example of a structurally characterized ferrocenyl pnictogen where three 1,2-disubstituted ferrocenyl groups are attached to the central antimony atom and phosphorus analogue of the stibine is missing in the literature. Stibine (1) shows a hypervalent Sb-N interaction while stibine (2) does not show this interaction in solid state. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.08.014
• 作为产物：
  描述：

  [α-(N,N-dimethylaminomethyl)ferrocenyl]lithium 、 三氯化锑 以 乙醚 为溶剂， 以59%的产率得到tris(1,2-N,N-dimethylaminomethylferrocenyl)stibine
  参考文献：
  名称：

  Tris-(1,2-N,N-dimethylaminomethylferrocenyl)stibine and its heterotrimetallic complex

  摘要：

  New tertiary chloro-bis(1,2-N, N-dimethylaminomethylferrocenyl)stibine (1) and tris-(1,2-N, N-dimethylaminomethylferrocenyl) stibine ligand (2) containing CH2NMe2 pendenant arm at the ortho-position have been synthesized. Stibine (2) reacts with PtCl42 and hetero trimetallic cis-PtCl2L (3) complex is obtained, where stibine (2) acts as a bidentate ligand. All these compounds were characterized by various physicochemical methods and their molecular structures were determined by X-ray diffraction analyses. It is to be noted that tris(1,2-aminomethylferrocenyl) stibine represents the first example of a structurally characterized ferrocenyl pnictogen where three 1,2-disubstituted ferrocenyl groups are attached to the central antimony atom and phosphorus analogue of the stibine is missing in the literature. Stibine (1) shows a hypervalent Sb-N interaction while stibine (2) does not show this interaction in solid state. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.08.014