[Mo(CO)2(η5-C5H5)]2[μ-(PhNP(OC6H4Me-p))]2 | 159564-35-9

• 英文名称: [Mo(CO)2(η5-C5H5)]2[μ-(PhNP(OC6H4Me-p))]2
• CAS: 159564-35-9
• 化学式: C₄₀H₃₄Mo₂N₂O₆P₂
• 分子量: 892.547
• InChiKey: AIZSGWDGTMLCSX-ZZEWSYKUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cyclopentadienylmolybdenum tricarbonyl dimer 、 1,3-Diphenyl-2,4-bis-p-tolyloxy-[1,3,2,4]diazadiphosphetidine 以 甲苯 为溶剂， 以65%的产率得到[Mo(CO)2(η5-C5H5)]2[μ-(PhNP(OC6H4Me-p))]2
  参考文献：
  名称：

  Organometallics of diphosphazanes. Part 10. Dinuclear group 6 metal carbonyl complexes bridged by a cyclodiphosphazane in its cis or trans form

  摘要：

  Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodiphosphazane ligand, [PhNP(OC(6)H(4)Me-p)](2) (L), have been used as synthons to prepare homo- and hetero-bimetallic complexes in which the cyclodiphosphazane bridges the two metal centres in its cis or trans isomeric forms. The dimolybdenum complex [Mo-2(eta(5)-C5H5)(2)(CO)(4)(mu-L)] has also been synthesized. The trends in P-31 NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed.

  DOI：

  10.1039/dt9940002661