| 648881-91-8

• CAS: 648881-91-8
• 化学式: C₁₂H₁₂Cl₈Ga₂Pd₂
• 分子量: 792.137
• InChiKey: OFRUCAUHLZAFQP-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 CO 作用下， 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Binuclear palladium(I) and platinum(I) dimers stabilized by aromatic ligands: synthesis, structural characterization and reactivity with carbon monoxide

  摘要：

  Reaction of PdCl2 with excess of GaCl3 in aromatic solvents leads to binuclear compounds of the general formula [Pd2X2(arene)(2)], where arene = C6H6, X- = GaCl7- (1); arene = C7H8, X- = GaCl4- (2). The solid-state structures of compounds 1 and 2 have been determined by X-ray crystallography. Two molecules of the arene are bound to the dipalladium unit. The compounds 1 and 2 do not react with triphenyl phosphine. Reaction of carbon monoxide with 1 in benzene solution yields [Pd-2(GaCl4)(2)(C6H6)(2)] (3), for which the crystal structure has also been determined. The compound [Pt-2(GaCl4)(2)(C10H10)(2)].2C(6)H(6) (4), which was obtained by reaction of K-2[PtCl4] with GaCl3 and naphthalene in a benzene solution, has a similar structure in the solid state. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01577-3