[CH3CCMg(((2,6-diisopropylphenyl)NCMe)2CH)] | 1334714-82-7

• 英文名称: [CH3CCMg(((2,6-diisopropylphenyl)NCMe)2CH)]
• CAS: 1334714-82-7
• 化学式: C₆₄H₈₈Mg₂N₄
• 分子量: 962.04
• InChiKey: MEPVAUAYIUUWCK-MNWBCHASSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲苯 、 trimethylamine alane 、 [CH3CCMg(((2,6-diisopropylphenyl)NCMe)2CH)] 以 甲苯 为溶剂， 以12%的产率得到[[(AlH)(AlH2)((2,6-diisopropylphenyl)N)3]2Mg]*4C7H8
  参考文献：
  名称：

  A β-diketiminato magnesium acetylide and formation of an imido aluminium magnesium hydride compound

  摘要：

  The reaction of LiC CMe with [((Dip)nacnac)MgI(OEt2)] ((Dip)nacnac = [(DipNCMe)(2)CH], Dip = 2,6-diisopropylphenyl) afforded [{((Dip)nacnac)MgC CMe}(2)] 1 in good yield. Treatment of 1 with AlH3 center dot NMe3 in toluene under reflux afforded a low yield of the novel imido aluminium magnesium hydride compound [{(AlH)(AlH2)(3)(NDip)(3)}(2)Mg] 2. The latter compound features a central Mg2+ ion that is coordinated via hydride ligands to two monoanionic [(AlH)(AlH2)(3)(NDip)(3)](-) fragments. The compounds have been characterised by H-1 and C-13 NMR spectroscopy, IR spectroscopy and the crystal structures of 1 and 2 center dot 4C(7)H(8) have been determined. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.047
• 作为产物：
  描述：

  [((Dip)nacnac)MgI(OEt2)] 、 丙炔 在 正丁基锂 作用下， 以 乙醚 、 甲苯 为溶剂， 以71%的产率得到[CH3CCMg(((2,6-diisopropylphenyl)NCMe)2CH)]
  参考文献：
  名称：

  A β-diketiminato magnesium acetylide and formation of an imido aluminium magnesium hydride compound

  摘要：

  The reaction of LiC CMe with [((Dip)nacnac)MgI(OEt2)] ((Dip)nacnac = [(DipNCMe)(2)CH], Dip = 2,6-diisopropylphenyl) afforded [{((Dip)nacnac)MgC CMe}(2)] 1 in good yield. Treatment of 1 with AlH3 center dot NMe3 in toluene under reflux afforded a low yield of the novel imido aluminium magnesium hydride compound [{(AlH)(AlH2)(3)(NDip)(3)}(2)Mg] 2. The latter compound features a central Mg2+ ion that is coordinated via hydride ligands to two monoanionic [(AlH)(AlH2)(3)(NDip)(3)](-) fragments. The compounds have been characterised by H-1 and C-13 NMR spectroscopy, IR spectroscopy and the crystal structures of 1 and 2 center dot 4C(7)H(8) have been determined. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.047