| 261913-72-8

• CAS: 261913-72-8
• 化学式: C₃₇H₃₃CoO₂
• 分子量: 568.661
• InChiKey: QGRXXDATDJTYCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  carbon monoxide,cobalt,cyclopenta-1,3-diene 、 4-(-Phenylethynyl)phenethyl alcohol 以 xylene 为溶剂， 以33%的产率得到
  参考文献：
  名称：

  寡核苷酸修饰的环丁二烯配合物的合成和自组装

  摘要：

  本文报道了寡核苷酸官能化的环丁二烯复合物及其与双链有机金属DNA物体的杂交。

  DOI：

  10.1021/om9909791

文献信息

• Oligonucleotide-Directed Assembly of Materials:  Defined Oligomers
  作者：Shane M. Waybright、Chainey P. Singleton、Kimberly Wachter、Catherine J. Murphy、Uwe H. F. Bunz

  DOI：10.1021/ja000950k

  日期：2001.3.1

  A nano-architectural system that has high variability while maintaining component specificity is described. Tetraphenylcyclobutadiene(cyclopentadienyl)cobalt complexes and phenyleneethynylene trimers were synthesized and subsequently modified with oligonucleotides utilizing standard phosphoramidite chemistry. The resulting oligonucleotide modified organics (OMOs) were characterized by UV-vis spectroscopy, fluorescence spectroscopy, and phosphate: analysis. Hybridization of these OMOs resulted in a series of self-assembled oligomeric hybrids of varying length and topology. These hybrids were characterized by melting temperature, polyacrylamide gel electrophoresis, and fluorescence spectroscopy. This model system demonstrates the power of DNA to self-assemble modules of interest-independent of the module itself.