[Ru(C5Me5)(P(m-tolyl)3)2(CH3CN)]PF6 | 952235-77-7

• 英文名称: [Ru(C5Me5)(P(m-tolyl)3)2(CH3CN)]PF6
• CAS: 952235-77-7
• 化学式: C₅₄H₆₀NP₂Ru*F₆P
• 分子量: 1031.06
• InChiKey: MKPKSENFUZMTDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate 、 三(间甲苯基)膦 以 丙酮 为溶剂， 以47%的产率得到[Ru(C5Me5)(P(m-tolyl)3)2(CH3CN)]PF6
  参考文献：
  名称：

  Reactions of Ru(Cp∗) complexes with P(o-tolyl)3

  摘要：

  Reaction of [Ru(Cp*)(CH3CN)(3)](PF6) with P(o-tolyl)(3) affords [Ru(Cp*) {eta(6)-o-tolyl]P(o-tolyl)(2))](PF6) (4) in which the P-atom is not coordinated to the metal. The solid-state structure of 4 has been determined. A related reaction with P(P-tolyl)3 reveals a small quantity [Ru(Cp*){(eta(6)-p-tolyl)P(o-tolyl)(2)}](PF6), in solution, but mostly the expected bis-phosphine complex. Reaction of the Ru(IV) dication, [Ru(Cp*)(eta(3) -PhCHCHCH2)(DMF)(2)](PF6)(2), with P(o-tolyl)(3) gives a mixture of the phosphonium salt, C6H5CH=CHCH2P(o-tolyl)(3) (9) and the dication [Ru(Cp*)(eta 6-C6H5CH=CHCH2P(o-tolyl)(3))](PF6)(2) (10)- Salt 9 forms via attack of the P-atom on the allyl ligand. The latter product results from complexation of 9 via the phenyl group of the former allyl ligand. It would seem that the sterically demanding P(o-tolyl)(3) ligand is not readily compatible with the Ru(Cp*) fragment, in either the +2 or +4 oxidation state. Detailed NMR studies are reported. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.003