dichlorodi(quinoxaline-2-carboxalidene-2-furfurylamine)manganese(II) | 211913-21-2

• 英文名称: dichlorodi(quinoxaline-2-carboxalidene-2-furfurylamine)manganese(II)
• CAS: 211913-21-2
• 化学式: C₂₈H₂₂Cl₂MnN₆O₂
• 分子量: 600.366
• InChiKey: CDBGIBWZDRWMGG-LAGLFLAWSA-L

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 quinoxaline-2-carboxalidene-2-furfurylamine 以 甲醇 、 丙酮 为溶剂， 以45%的产率得到dichlorodi(quinoxaline-2-carboxalidene-2-furfurylamine)manganese(II)
  参考文献：
  名称：

  Studies on Some Transition Metal Complexes of Schiff Bases Derived from Quinoxaline‐2‐carboxaldehyde

  摘要：

  Two series of transition metal complexes of Schiff bases derived from quinoxaline-2-carboxaldehyde with semicarbazide QSC) and furfurylamine QFA) were synthesised and characterised by elemental analyses, molar conductance and magnetic susceptibility measurements, IR, electronic and EPR spectral studies. The QSC complexes have the general formula [M(QSC)Cl-2]. A tetrahedral structure has been assigned for the Mn(II), Co(II) and Ni(II) complexes and a square-planar structure for the Cu(II) complex. The QFA complexes have the formula [M(QFA)(2)Cl-2]. An octahedral structure has been assigned for these complexes. All of the complexes exhibit catalytic activity towards the oxidation of 3,5-di-tert-butylcatechol (DTBC) to 3,5-di-tert-butylquinone (DTBQ) using atmospheric oxygen. The cobalt(II) complex of the ligand QFA was found to be the most active catalyst.

  DOI：

  10.1081/sim-120020000