(1,3-bis(4-acetylphenyl)triaz-2-en-1-yl)bis(triphenyl-l5-phosphaneyl)palladium(IV) chloride | 1352513-44-0

• 英文名称: (1,3-bis(4-acetylphenyl)triaz-2-en-1-yl)bis(triphenyl-l5-phosphaneyl)palladium(IV) chloride
• CAS: 1352513-44-0
• 化学式: C₅₂H₄₄ClN₃O₂P₂Pd
• 分子量: 946.761
• InChiKey: RGWDEBDYPOAZAH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,3-bis(4-acetylphenyl)triazene 、 bis-triphenylphosphine-palladium(II) chloride 在 triethylamine 作用下， 以 甲醇 为溶剂， 以68%的产率得到(1,3-bis(4-acetylphenyl)triaz-2-en-1-yl)bis(triphenyl-l5-phosphaneyl)palladium(IV) chloride
  参考文献：
  名称：

  Three-dimensional triazenido layers attained through classical and non-classical hydrogen interactions and its coordination to palladium under prolific occurrence of bifurcated hydrogen bonding

  摘要：

  The new ligand 1,3-bis(3-methoxy-4-methylbenzoate) triazene (1, bmmbt), and the already known ligand 1,3-bis(4-acetylphenyl)triazene (bapht), yield the two new palladium(II) complexes [(bmmbt)Pd(PPh3)(2)Cl]center dot DMSO (2) and [(bapht)Pd(PPh3)(2)Cl] (3) (Ph = phenyl; DMSO = dimethylsulfoxide). Compound 1 shows the existence of more than one interaction promoting the coupling between the triazene chains. Other remarkable types of interactions in 1 are bifurcated hydrogen contacts and non-classical CH center dot center dot center dot pi bonding. Complexes 2 and 3 present a planar geometry, supported also through bifurcated intramolecular Cl center dot center dot center dot H-C interactions, as well as the occurrence of trifurcated Cl center dot center dot center dot H-C intermolecular interactions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.10.009