[FeCHCH(4-(N-(4-t-butylbenzyl)pyridinium))]BF4 | 214194-17-9

• 英文名称: [FeCHCH(4-(N-(4-t-butylbenzyl)pyridinium))]BF4
• CAS: 214194-17-9
• 化学式: BF₄*C₂₈H₃₀FeN
• 分子量: 523.205
• InChiKey: XPLUAVOKVJQWTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [FeCHCH(4-(N-(4-t-butylbenzyl)pyridinium))]BF4 、 四丁基高氯酸铵 以 乙腈 为溶剂， 生成 trans-[FeCHCH(4-(N-(4-t-butylbenzyl)pyridinium))]ClO4
  参考文献：
  名称：

  Organometallic color chemistry: studies on [FcCHCHC5H4NCH2C6H4(tBu)]X (X=BPh4−, ClO4−)

  摘要：

  The title dyes, [FcCH=CHC5H4NCH2C6H4('Bu)]X (X = BPh4-, ClO4-), developed for rapid screening of catalysts, are intensely colored, but bleach on exposure to visible light in solution. Detailed study shows that on irradiation these alkene dyes first undergo a trans-cis isomerization, then give an irreversible bleaching via decomposition. Both dyes show color dependence on the nature of the anion as a result of ion-pairing, which affects the intensity and position of the visible absorption. NMR, MS and EPR data are also reported. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00422-8
• 作为产物：
  描述：

  [Fc-CHCH(4-(N-(4-t-butylbenzyl)pyridinium))]Br 、 silver tetrafluoroborate 以 丙酮 为溶剂， 以90%的产率得到[FeCHCH(4-(N-(4-t-butylbenzyl)pyridinium))]BF4
  参考文献：
  名称：

  Organometallic color chemistry: studies on [FcCHCHC5H4NCH2C6H4(tBu)]X (X=BPh4−, ClO4−)

  摘要：

  The title dyes, [FcCH=CHC5H4NCH2C6H4('Bu)]X (X = BPh4-, ClO4-), developed for rapid screening of catalysts, are intensely colored, but bleach on exposure to visible light in solution. Detailed study shows that on irradiation these alkene dyes first undergo a trans-cis isomerization, then give an irreversible bleaching via decomposition. Both dyes show color dependence on the nature of the anion as a result of ion-pairing, which affects the intensity and position of the visible absorption. NMR, MS and EPR data are also reported. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00422-8