| 149924-53-8

• CAS: 149924-53-8
• 化学式: C₁₀H₁₅B₉MnO₆Rh
• 分子量: 486.368
• InChiKey: HHDDUGLUZQXLDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基溴化锰(I) 、 在 TlBF₄ 作用下， 以 二氯甲烷 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  (Carbaborane)rhodium-copper and -manganese complexes: Crystal structure of [RhCu(PPh3)(cod)(η5-7,8-C2B9H9Me2)]

  摘要：

  Treatment of [CuCl(PPh3)] with [NEt4][Rh(cod)(eta5-7,8-C2B9H9Me2)] (Cod = cyclo-octa-1,5-diene) in CH2Cl2 in the presence of TlBF4 affords the dimetal compound [RhCu(PPh3)(Cod)(eta5-7,8-C2B9H9Me2)], the structure of which has been established by X-ray diffraction (Rh-Cu 2.633(2) angstrom, Rb-Cu-P 153.3(1)-degrees). Reactions between [MnBr(CO)5] and the tetraethylammonium salts of the complexes [Rh(CO)(PPh3)(eta5-7,8-C2B9H9Me2)]- and [Rh(cod)(eta5-7,8-C2B9H9Me2)]- yield the dimetal compounds [MnRh(CO)5(L)(eta5 -7,8-C2B9H9Me2)] (L=PPh3 or CO) respectively. Treatment of [Mn(CO)2(NO)(eta5-C5H4Me)][BF4] with INEt4][Rh(CO)(PPh3)(eta5-7,8-C2B9H9Me2)] affords [Rh(NO)(PPh3)(eta5-7,8-C2B9H9Me2)], in an unusual reaction involving transfer of the NO ligand from manganese to rhodium.

  DOI：

  10.1016/0022-328x(93)83027-s