| 714964-11-1

• CAS: 714964-11-1
• 化学式: BF₄*C₁₉H₁₆FeN
• 分子量: 400.994
• InChiKey: BJQKYFBGOQLQLG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 sodium ethanolate 以 乙醇 、 乙腈 为溶剂， 以95%的产率得到ethoxy(indol-3-yl)ferrocenylmethane
  参考文献：
  名称：

  Properties of α-Ferrocenylcarbenium and Ferricinium Salts by Nonaqueous Potentiometric Titration

  摘要：

  Potentiometric titration of alpha-ferrocenylcarbenium and ferricinium salts in anhydrous acetonitrile with sodium ethylate involves redox reaction between the titrate and titrant, which, once equimolar amount of the latter has been added, produces a potential jump of 300-400 mV (platinum indicator electrode). The oxidation potentials of the alpha-ferrocenylcarbenium and ferricinium salts in anhydrous acetonitrile were estimated at 410-500 mV. The experimental data gave evidence for intramolecular redox processes (redox tautomerism) in the compounds studied.

  DOI：

  10.1023/b:rugc.0000016023.02955.6e