[Co2Fe(μ3-SPPh2)(.mu-PPh2)(CO)7] | 406915-04-6

• 英文名称: [Co2Fe(μ3-SPPh2)(.mu-PPh2)(CO)7]
• CAS: 406915-04-6
• 化学式: C₃₁H₂₀Co₂FeO₇P₂S
• 分子量: 772.343
• InChiKey: MMZNQXNDASWSPE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Co2Fe(μ3-S)(.mu-PPh2)2(CO)6] 、 一氧化碳 以 甲苯 为溶剂， 以28%的产率得到[Co2Fe(μ3-SPPh2)(.mu-PPh2)(CO)7]
  参考文献：
  名称：

  一pH值对磷-氢键裂解2 PH-取代μ 3 -thioxo八羰基二铁簇作为路由到桥接膦和thiophosphine配体

  摘要：

  The secondary phosphine-substituted (at cobalt) mixed-metal dicobalt–iron complex [Co2Fe(μ3-S)(CO)8(PPh2H)] (1) can be prepared in good yield from the reaction of [Co2Fe(μ3-S)(CO)9] with one equivalent of Ph2PH in toluene. Also isolated in the reaction, as minor products, are the disubstituted (both at cobalt) complex [Co2Fe(μ3-S)(CO)7(PPh2H)2] (2) and the trisubstituted species [Co2Fe(μ3-S)(CO)6(PPh2H)3]

  DOI：

  10.1016/s0022-328x(01)01227-x