μ3-benzylimido-tris[(trimethylphosphine)gold(I)] tetrafluoroborate | 161959-40-6

• 英文名称: μ3-benzylimido-tris[(trimethylphosphine)gold(I)] tetrafluoroborate
• CAS: 161959-40-6
• 化学式: BF₄*C₁₆H₃₄Au₃NP₃
• 分子量: 1011.08
• InChiKey: KLDRCZLBVWZYPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  μ3-benzylimido-tris[(trimethylphosphine)gold(I)] tetrafluoroborate 在 H₂O 作用下， 以 二氯甲烷 为溶剂， 生成 μ-benzylamido-bis[(trimethylphosphine)gold(I)] tetrafluoroborate
  参考文献：
  名称：

  Primary amines as nucleation centres for gold clustering, and the structural chemistry of polygold ammonium cations

  摘要：

  Treatment of tert-butylamine and benzylamine with [Au(PR'3)]BF4 led to the monoauration products [(R'3P)AuNH2R]+BF4- (R' = Me, R = Bu(t) 1a; R' = Me, R = CH2Ph 1b; R'3 = Ph2Me, R = Bu(t) 1c). The salts [{Au(PMe3)}3NR]+BF4- (R' = Me, R = Bu(t) 2a or CH2Ph 2b) derived from the same amines were obtained using the corresponding oxonium salt [{Au(PMe3)}3O]+BF4-. A diauration product [{Au(PMe3)}2NH(CH2Ph)]+BF4- 3 was generated upon slow hydrolytic degradation of 2b in solution. Treatment of NH(SiMe3)2 with [{Au(PMe3)}3O]+BF4- afforded both the tris- and tetra-aurated ammonium salts, [{Au(PMe3)}3NSiMe3]+BF4- 2c and [{Au(PMe3)}4N]+BF4- 4, depending on the reaction conditions. The cation of 2c is one of the very rare examples of silylammonium species. Compound 4 was also obtained from the oxonium salt and ammonia. All compounds have been characterized through analytical and spectroscopic data. The crystal structures of 1a, 1c and 3 have been determined by X-ray diffraction methods: 1c is a salt with monomeric gold ammonium cations, but 1a and 3 show supramolecular aggregation of the cations into dimers with short intercationic Au ... Au contacts.

  DOI：

  10.1039/dt9950000559
• 作为产物：
  描述：

  tris[(trimethylphosphane)gold(I)]oxonium tetrafluoroborate 、 苄胺 以 二氯甲烷 为溶剂， 以79%的产率得到μ3-benzylimido-tris[(trimethylphosphine)gold(I)] tetrafluoroborate
  参考文献：
  名称：

  Primary amines as nucleation centres for gold clustering, and the structural chemistry of polygold ammonium cations

  摘要：

  Treatment of tert-butylamine and benzylamine with [Au(PR'3)]BF4 led to the monoauration products [(R'3P)AuNH2R]+BF4- (R' = Me, R = Bu(t) 1a; R' = Me, R = CH2Ph 1b; R'3 = Ph2Me, R = Bu(t) 1c). The salts [{Au(PMe3)}3NR]+BF4- (R' = Me, R = Bu(t) 2a or CH2Ph 2b) derived from the same amines were obtained using the corresponding oxonium salt [{Au(PMe3)}3O]+BF4-. A diauration product [{Au(PMe3)}2NH(CH2Ph)]+BF4- 3 was generated upon slow hydrolytic degradation of 2b in solution. Treatment of NH(SiMe3)2 with [{Au(PMe3)}3O]+BF4- afforded both the tris- and tetra-aurated ammonium salts, [{Au(PMe3)}3NSiMe3]+BF4- 2c and [{Au(PMe3)}4N]+BF4- 4, depending on the reaction conditions. The cation of 2c is one of the very rare examples of silylammonium species. Compound 4 was also obtained from the oxonium salt and ammonia. All compounds have been characterized through analytical and spectroscopic data. The crystal structures of 1a, 1c and 3 have been determined by X-ray diffraction methods: 1c is a salt with monomeric gold ammonium cations, but 1a and 3 show supramolecular aggregation of the cations into dimers with short intercationic Au ... Au contacts.

  DOI：

  10.1039/dt9950000559