| 1318655-58-1

• CAS: 1318655-58-1
• 化学式: C₂₆H₂₄Cl₄Fe₂N₂O₄
• 分子量: 681.994
• InChiKey: PXZFHCZVXOMDRA-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  以 丙酮 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Highly flexible O,O′,N ligands and their Fe, Ni, Cu and Zn complexes

  摘要：

  Three new chiral ligands bearing an O,O',N donor set (OmethoxyOhydroxyNpyridine) were synthesised and coordinated to Fe-III, Fe-II, Ni-II, Cu-II and Zn-II to yield complexes with the general formula [M(OON)Cl-x](y). While the pyridine N and the hydroxy O atoms coordinate strongly to all applied metal ions, the methoxy donor seems not to be involved in coordination, although some evidence for a weak interaction between O-Me and the Zn-II were found in NMR spectra. In the bidentate O', N coordination mode the new ligands exhibit several coordination geometries as analysed in the solid compounds by XRD, EXAFS and EPR and in solution by UV-Vis absorption, cyclic voltammetry, EXAFS, EPR or NMR spectroscopy. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.072