[Pd(5-(COH)C6H3C(H)=NCy-C2,N)(cis-bis(diphenylphosphine)ethene-P,P)][PF6] | 521070-24-6

• 英文名称: [Pd(5-(COH)C6H3C(H)=NCy-C2,N)(cis-bis(diphenylphosphine)ethene-P,P)][PF6]
• CAS: 521070-24-6
• 化学式: C₄₀H₃₈NOP₂Pd*F₆P
• 分子量: 862.08
• InChiKey: SVAFKXIYVVAHPX-JRPLLSPXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [Pd(5-(COH)C6H3C(H)N(cyclohexyl)-C2,N)(μ-Cl)]2 、 顺-1,2-双(二苯基膦)乙烯 在 silver trifluorosulfonate 作用下， 以 丙酮 为溶剂， 以57%的产率得到[Pd(5-(COH)C6H3C(H)=NCy-C2,N)(cis-bis(diphenylphosphine)ethene-P,P)][PF6]
  参考文献：
  名称：

  Functionalized cyclopalladated compounds with bidentate Group 15 donor atom ligands: the crystal and molecular structures of [{Pd[5-(COH)C6H3C(H)NCy-C2,N](Cl)}2(μ-Ph2PRPPh2)] (R=CH2CH2, Fe(C5H4)2], [Pd{5-(COH)C6H3C(H)NCy-C2,N}(Ph2PCH2PPh2-P,P)][PF6] and [Pd{5-(COH)C6H3C(H)N(Cy)-C2,N}(Ph2PCH2CH2AsPh2-P,As)][PF6]

  摘要：

  The chloro-bridged dinuclear compound [{Pd[5-(COH)C6H3C(H) =N(Cy)-C2,N]}(mu-Cl)](2) (1), reacts with tertiary diphosphines in 1:1 molar ratio to give [{Pd[5-(COH)C6H3C(H)=NCy-C2,N](Cl)}(2)(mu-Ph2PRPPh2)] (R: CH2,2; CH2CH2,3; (CH2)(4),4; (CH2)(6),5; Fe(C5H4)(2), 6; trans-CH=CH, 7; C drop C, 8). Treatment of 1 with Ph2PCH2CH2AsPh2 (arphos) gives the dinuclear complex [{Pd[(5)(COH)C6H3C(H)=N(Cy)-C2,N](Cl)}(2)(mu-Ph2PCH2CH2AsPh2)] (9). The reaction of 1 with tertiary diphosphines or arphos in 1:2 molar ratio in the presence of NH4PF6 yields the mononuclear compounds [Pd{5-(COH)C6H3C(H)=NCy-C2,N}(Ph2PRPPh2-P,P)][PF6] (R: (CH2)(4), 10; (CH2)(6), 11; Fe(C5H4)(2),12; 1,2-C6H4,13; cis-CH=CH, 14; NH, 15) and [Pd{5-(COH)C6H3C(H)=N(Cy)-C2,N}(Ph2PCH2CH2AsPh2-P,As)][PF6](16). H-1-, P-31-{H-1}- and C-13-{H-1}-NMR, IR and mass spectroscopic data are given. The crystal structures of compounds 3, 6, 9 and 16 have been determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02065-x