[(1,1'-dimethyl-3,3'-(1,3-trimethylene)diimidazoline-2,2'-diylidene)(AgCl)2] | 914500-04-2

• 英文名称: [(1,1'-dimethyl-3,3'-(1,3-trimethylene)diimidazoline-2,2'-diylidene)(AgCl)2]
• CAS: 914500-04-2
• 化学式: C₁₁H₁₆Ag₂Cl₂N₄
• 分子量: 490.917
• InChiKey: LNZPJKWSWNZDMX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 [(1,1'-dimethyl-3,3'-(1,3-trimethylene)diimidazoline-2,2'-diylidene)(AgCl)2] 以 二甲基亚砜 为溶剂， 以92%的产率得到1,1'-dimethyl-3,3'-(1,3-trimethylene)diimidazoline-2,2'-diylidenepalladium(II) dichloride
  参考文献：
  名称：

  Extension of the Alkane Bridge in BisNHC−Palladium−Chloride Complexes. Synthesis, Structure, and Catalytic Activity

  摘要：

  A series of bisNHC chelate ligands with alkyl bridges of different chain lengths and their palladium complexes have been prepared. The influence of the different bridges on the solid-state structure and reactivity of the complexes has been studied. The catalytic activity of the palladium complexes was successfully tested in the Mizoroki-Heck reaction and the catalytic CH activation of methane. The ethylene-bridged palladium complex showed the highest catalytic activity in the CH activation of methane and the Mizoroki-Heck coupling of bromoarenes, while for unreactive chloroarenes bisNHC complexes with longer bridges give better results.

  DOI：

  10.1021/om060577a
• 作为产物：
  描述：

  1,1'-dimethyl-3,3'-(1,3-trimethylene)bisimidazolium dichloride 、 silver(l) oxide 以 乙腈 为溶剂， 以93.3%的产率得到[(1,1'-dimethyl-3,3'-(1,3-trimethylene)diimidazoline-2,2'-diylidene)(AgCl)2]
  参考文献：
  名称：

  Extension of the Alkane Bridge in BisNHC−Palladium−Chloride Complexes. Synthesis, Structure, and Catalytic Activity

  摘要：

  A series of bisNHC chelate ligands with alkyl bridges of different chain lengths and their palladium complexes have been prepared. The influence of the different bridges on the solid-state structure and reactivity of the complexes has been studied. The catalytic activity of the palladium complexes was successfully tested in the Mizoroki-Heck reaction and the catalytic CH activation of methane. The ethylene-bridged palladium complex showed the highest catalytic activity in the CH activation of methane and the Mizoroki-Heck coupling of bromoarenes, while for unreactive chloroarenes bisNHC complexes with longer bridges give better results.

  DOI：

  10.1021/om060577a