chlorogallane;N,N-dimethylmethanamine | 19528-09-7

• 英文名称: chlorogallane;N,N-dimethylmethanamine
• CAS: 19528-09-7
• 化学式: C₃H₁₁ClGaN
• 分子量: 166.303
• InChiKey: YIQWSUNNYJBWQS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.05
• 重原子数：
  6.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  chlorogallane;N,N-dimethylmethanamine 、 三甲胺 以 neat (no solvent) 为溶剂， 生成 chlorogallane;N,N-dimethylmethanamine
  参考文献：
  名称：

  Some Chemical Properties of Monochlorogallane:  Decomposition to Gallium(I) Trichlorogallate(III), Ga⁺[GaCl₃H]^-, and Other Reactions

  摘要：

  Thermal decomposition of monochlorogallane, [H2GaCl](n), at ambient temperatures releases H-2 and results in the formation of gallium(I) species, including the new compound Ga[GaHCl3], which has been characterized crystallographic ally at 100 K (monoclinic P2(1)/n, a = 5.730(1), b = 6.787(1), c = 14.508(1) Angstrom, beta = 97.902(5)degrees) and by its Raman spectrum. The gallane suffers symmetrical cleavage of the Ga(mu -Cl)(2)Ga bridge in its reaction with NMe3 but unsymmetrical cleavage, giving [H2Ga(NH3)(2)]Cl-+(-), in its reaction with NH3. Ethene inserts into the Ga-H bonds to form first [Et(H)GaCl](2) and then [Et2GaCl](2).

  DOI：

  10.1021/ic010128x
• 作为产物：
  描述：

  monochlorogallane 、 三甲胺 以 neat (no solvent) 为溶剂， 生成 chlorogallane;N,N-dimethylmethanamine
  参考文献：
  名称：

  Some Chemical Properties of Monochlorogallane:  Decomposition to Gallium(I) Trichlorogallate(III), Ga⁺[GaCl₃H]^-, and Other Reactions

  摘要：

  Thermal decomposition of monochlorogallane, [H2GaCl](n), at ambient temperatures releases H-2 and results in the formation of gallium(I) species, including the new compound Ga[GaHCl3], which has been characterized crystallographic ally at 100 K (monoclinic P2(1)/n, a = 5.730(1), b = 6.787(1), c = 14.508(1) Angstrom, beta = 97.902(5)degrees) and by its Raman spectrum. The gallane suffers symmetrical cleavage of the Ga(mu -Cl)(2)Ga bridge in its reaction with NMe3 but unsymmetrical cleavage, giving [H2Ga(NH3)(2)]Cl-+(-), in its reaction with NH3. Ethene inserts into the Ga-H bonds to form first [Et(H)GaCl](2) and then [Et2GaCl](2).

  DOI：

  10.1021/ic010128x

文献信息

• Synthesis, Structure, and Properties of Gallium Compounds with the Heterodifunctional [2-(<i>N</i>,<i>N</i>-Dimethylamino)ethyl]cyclopentadienyl Ligand¹
  作者：Peter Jutzi、Michael Bangel、Beate Neumann、Hans-Georg Stammler

  DOI：10.1021/om960497e

  日期：1996.10.15

  Several new gallium compounds containing the [2-(N,N-dimethylamino)ethyl]cyclopentadienyl ligand (CpN) are described. Reaction of the respective element halide with CpNK 1 leads to the compounds 2−6 of the type [2-(Me2NCH2CH2)C5H4]GaX2 [2:  X = Cl; 3:  X = Br; 4:  X = I; 5:  X = CH3; 6:  X = H]. Each compund was characterized by 1H and 13C NMR spectroscopy, mass spectrometry, and elemental analysis;

  描述了几种新的含[2-（N，N-二甲基氨基）乙基]环戊二烯基配体（Cp N）的镓化合物。再用Cp相应元件卤化物反应Ñ ķ 1个通向化合物2-6的类型的[2-（ME 2 NCH 2 CH 2）C 5 H ^ 4 ] GAX 2 [ 2：X =氯; 3：X ＝ Br；4：X = I；5：X = CH 3 ; 6：X ＝ H]。每个化合物的特征是1 H和13C NMR光谱，质谱和元素分析；X射线晶体学确定2-5的分子结构。在固态并且大概也在溶液中，所有化合物均具有带有分子内配位的二甲基氨基的单体结构。所产生的金属中心的配位和电子饱和导致与湿气和空气的反应性大大降低。解决方案中观察到的动态行为基于“挡风玻璃刮水器”类型过程中的快速触觉变化。充分的挥发性和良好的碎裂性使6成为MOCVD工艺中镓沉积的合适前体。
• Monochlorogallane: synthesis, properties, and structure of the dimer H₂Ga(µ-Cl)₂GaH₂in the gas phase as determined by electron diffraction
  作者：Michael J. Goode、Anthony J. Downs、Colin R. Pulham、David W. H. Rankin、Heather E. Robertson

  DOI：10.1039/c39880000768

  日期：——

  Monochlorogallane, synthesised by metathesis involving gallium(III) chloride and trimethylsilane, has been characterised by its spectroscopic and chemical properties; electron diffraction has established the structure of the dimer H2Ga(µ-Cl)2GaH2, the predominant vapour species at low pressure.

  通过氯代镓（III）和三甲基硅烷的复分解合成的一氯代gallane具有光谱和化学性质。电子衍射已经建立了二聚体H 2 Ga（µ-Cl）2 GaH 2的结构，这是低压下的主要蒸汽物质。
• Fischer, Roland A.; Miehr, Alexander; Priermeier, Thomas, Chemische Berichte, 1995, vol. 128, # 8, p. 831 - 844
  作者：Fischer, Roland A.、Miehr, Alexander、Priermeier, Thomas

  DOI：——

  日期：——