[Cu(aqphen)₂Cl]Cl | 1446446-17-8

• 英文名称: [Cu(aqphen)₂Cl]Cl
• 英文别名: [Cu(12,17-dihydronaphthol[2,3-h]dipyrido[3,2-a:2′,3′-c]-phenazine-12,17-dione)₂Cl]Cl
• CAS: 1446446-17-8
• 化学式: C₅₂H₂₄ClCuN₈O₄*Cl
• 分子量: 959.266
• InChiKey: OKJVRIZPVZFSND-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 naphtha[2,3-a]dipyrido[3,2-h:2′,3′-f]phenazine-5,18-dione 在 三乙胺 作用下， 以 乙醇 、 水 为溶剂， 反应 5.0h， 以63%的产率得到[Cu(aqphen)₂Cl]Cl
  参考文献：
  名称：

  The coupling of carbon dioxide and epoxides by phenanthroline derivatives containing different Cu(II) complexes as catalyst

  摘要：

  A series of the mononuclear Cu(II) metal complexes containing the ligand Bdppz [(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)-phenyl-methanone] (L-1) and Aqphen [(12,17-dihydronaphthol[2,3-h]dipyrido[3,2-a:2',3'-c]-phenazine-12,17-dione)] (L-2) were synthesized and used as catalyst for the coupling of carbon dioxide (CO2) and liquid epoxide which served as both reactant and solvent. Dimethylamino pyridine (DMAP) was used as co-catalyst. The yields of epoxides to corresponding cyclic carbonates were determined by comparing the ratio of product to substrate in the H-1 NMR spectrum of an aliquot of the reaction mixture. The mononuclear Cu(II) complexes of these ligands were synthesized by treating an ethanol solvent of the appropriate ligand with a different molar amount of CuCl2 center dot 2H(2)O. The Cu(II) complexes were characterized by FT-IR, UV-Vis, elemental analysis, melting point analysis, mass spectra, molar conductivity measurements and magnetic susceptibility techniques. The reaction of the Bdppz and Aqphen ligands in a 1:1, 1:2 or 1:3 mole ratio with CuCl2 center dot 2H(2)O afforded ionic Cu(II) complexes in the presence of Et3N. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2013.04.124